新型软质抗静电聚氯乙烯材料的研究Studyon-上海有机化学研究所.PDFVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第10 期, 979～982 ACTA CHIMICA SINICA No. 10, 979～982 ·研究论文· 新型软质抗静电聚氯乙烯材料的研究 周世一 雷景新* 孙中武 李启满 ( 四川大学高分子研究所高分子材料工程国家重点实验室 成都 610065) 摘要 合成了一种长链季铵盐类化合物, 将其用作抗静电剂添加到软质聚氯乙烯(PVC)材料中, 测试了材料的表面电 阻、力学性能, 并采用扫描电子显微镜测试研究了其结构. 结果表明: 随合成长链季铵盐的添加量增大, PVC 材料的表 面电阻率降低, 较小的添加量(4.5%)即可使材料的表面电阻率降低至 3.0 ×108 Ω 以下, 达到了煤矿行业对高分子材料 抗静电性能的要求. 在上述抗静电 PVC 材料中添加一定量的聚氧化乙烯(PEO), 可以降低抗静电材料对环境湿度的依 赖性, 并提高PVC 材料的力学性能和抗静电性能. 关键词 季铵盐; 软质聚氯乙稀; 表面电阻率; 抗静电性; PEO Study on Novel Soft Poly(vinyl Chloride) with Antistatic Property ZHOU, Shi-Yi LEI, Jing-Xin* SUN, Zhong-Wu LI, Qi-Man (State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065) Abstract A quaternary ammonium salt compound with a long chain of 12 carbon atoms was synthesized and used as an antistatic agent to be added into plasticized poly(vinyl chloride) (PVC), and the structure and properties of such PVC materials were studied by surface resistivity, mechanical property and scanning electronic microscope tests. The results show that with the content of the synthetic compound increasing, the surface resistivity of PVC materials was decreased. When the content of the synthetic compound reached 8 4.5%, the surface resistivity of PVC materials was reduced below 3.0 ×10 Ω. When a small amount of