基于fe、co、ni的电催化析氢催化剂的研究进展 recent progress in the electrocatalysts based on fe, co and ni for electrocatalytic hydrogen evolution reaction.pdfVIP
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基于fe、co、ni的电催化析氢催化剂的研究进展 recent progress in the electrocatalysts based on fe, co and ni for electrocatalytic hydrogen evolution reaction
本文引用格式:张晓,何小波,李响,等 . 基于 Fe、Co、Ni 的电催化析氢催化剂的研究进展 [J]. 新型工业化,2016,6(10):1-9.
DOI: 10.19335/ki.2095-6649.2016.10.001
基于Fe、Co、Ni的电催化析氢催化剂的研究
进展
张晓 1 ,何小波 2,3 ,李响 3 ,银凤翔 1,2,3
(1. 北京化工大学有机无机复合材料国家重点实验室,北京 100029;2. 先进催化与绿色制造协同创新中心,常州大学,江
苏 常州 213164;3. 北京化工大学常州先进材料研究院,江苏 常州 213164)
摘要:氢能经济的快速发展有赖于经济可行的制氢技术。研发低成本、高性能的电催化析氢催化剂对提升制
氢技术,促进氢能经济的发展具有重要意义。本文综述了近几年发展的非贵金属电催化析氢催化剂,重点介绍了
基于过渡金属 Fe、Co 和 Ni 的合金、磷化物以及硫化物等电催化析氢催化剂的研究和发展情况,对它们的合成方法、
结构特性、催化活性、稳定性能以及微观结构和析氢性能之间的关系进行了深入探讨。分析表明,基于过渡金属
Fe、Co、Ni 的催化剂尽管具有极大的成本优势,但是它们的析氢催化性能目前仍然低于贵金属催化剂,离实际应
用的要求还有一定距离。随着材料、化学学科的发展、合成技术的创新以及析氢催化机理研究的深入,基于过渡
金属催化剂的析氢催化性能必将取得重大突破。
关键词:制氢;电化学;过渡金属;催化剂;氢气析出反应
Recent Progress in The Electrocatalysts Based on Fe, Co and Ni for Electrocatalytic
Hydrogen Evolution Reaction
1 2, 3 2 1, 2, 3
Zhang Xiao , he Xiao-bo , Li Xiang , Yin Feng-xiang
1 2
( State Key Laboratory of Organic-inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China; Chang-
zhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou 213164, Jiangsu, China; 3 Changzhou
University, Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, Changzhou 213164, Jiangsu, China)
abstract: The development of hydrogen energy is mainly depended on the economically feasible hydrogen production
technologies. The low-cost electrocatalysts with high performance for electrocatalytic hydrogen evolution reaction (heR)
play an important role in improving hydrogen production technologies and thus promoting hydrogen economy. in this paper,
the development of non-precious metal electrocatalysts for heR in recent years was reviewed. The discussion was focused
on the electrocatalysts based on Fe, Co and ni transition metals, includi
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