柠檬酸的检测（Determination of citric acid）.docVIP

下载本文档

6
0
约1.75万字
约 19页
2017-09-15 发布于河南
举报
版权申诉

柠檬酸的检测（Determination of citric acid）.doc

1、本文档共19页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
5、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
6、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
7、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
8、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

柠檬酸的检测（Determination of citric acid）

柠檬酸的检测（Determination of citric acid） 2 the water used in the test is distilled water or ion exchange water. 2.1 differential test 2.1.1 reagents and Solutions 2.1.1.1 sulfuric acid (GB 625); 2.1.1.2 mercury sulfate: 5g Santar (HG3-1069), add 40ml of water, and then slowly add 20ml of sulfuric acid, stir, add 40ml of water and stir to dissolve; Potassium Permanganate 2.1.1.3 (GB 643): 0.1N solution; 2.1.1.4 sodium hydroxide (GB 629): 4.3% (W/V) solution; 2.1.1.5 acetic anhydride (GB 677); 2.1.1.6 pyridine (GB 689); 2.1.1.7 sample solution: citric acid 5mg per milliliter. 2.1.2 test procedure 2.1.2.1 take a small amount of samples, with straight Huochi burning, which slowly decompose, but no odor of caramel. 2.1.2.2 take sample solution 2ml, with 4.3% sodium hydroxide solution to neutral, add 1 drops of dilute sulfuric acid, heated to boiling. Add 1 drops of 0.1N Potassium Permanganate solution, shaking, purple subsided. Add 1 drops of mercury sulfate solution to produce white precipitate. 2.1.2.3 samples 5mg, pyridine and acetic anhydride (3:1) about 5ml, which generates yellow to red or purple red solution. 2.2 content 2.2.1 reagents and Solutions 2.2.1.1 sodium hydroxide standard solution (GB 629): 1N solution, prepared and calibrated according to GB 601 standard solution preparation method; Phenolphthalein 2.2.1.2 (HGB 3039): 1% (W/V) was prepared according to GB 603 preparation and product preparation method. 2.2.2 test procedure weigh 1.5g sample (referred to 0.0002g), adding neutral 50ml dissolved in distilled water, add 3 drops of phenolphthalein solution with 1N 1%, sodium hydroxide standard solution titration to pink end point. 2.2.3 calculation V * C * 0.06404 X1 = - - - * 100....................................... (1) M (1-0.08566) V * C * 0.06404 X2 = - - - - * 100.......................................... (2) M Formula: X1 - citric acid content (by anhydrous),%; X2 - anhydrous citric acid content,%; V - the amount of standard solution of sodium hydroxide