钾长石分解反应热力学及过程评价.pdfVIP

21 2 Vol21 No2 2007 6 GEOSCIENCE Jun2007 马鸿文, 苏双青, 王 芳, 徐锦明, 谭丹君, 刘 浩 ( , 100083) : Gibbs, , : ; , CO , 2 , : ; ; ; ; : TQ1701 : A : 1000- 8527( 2007) 02- 0426- 09 Thermodynam ic Analysis on Decomposition reactions of Potassium Feldspar and Evaluation of the Processes MA Hongwen, SU Shuangqing, WANG Fang, XU Jin ing, TAN Danjun, LIU Hao (N ationalLaboratory of M ineralM aterials, China University of Geosciences, B eij ing 100083, China) Abstract: The advances of ther al deco position of potassiu feldsparw ith various additive agents are re viewed. Ther odyna ic calculations of the ther aldeco position reactions ofpotassiu feldspar are perfor ed for both of theGibbs free energy changes and energy consu ptions during the sintering processesw ith various additives. Taking such factors into consideration as ineral resource consu ption, energy consu ption, envi ron ental co patibility, and the ter inalproductsche a for thesinteringprocedures ofpotassiu feldspar pow dery aterials, it is deduced that both proceduresw ith li estone and sodiu carbonateas additives are of signi ficance in industry; and further, it is onlywhen sodiu carbonate is taken as additive that the procedure could be the least consu ptions of the ineral resources and energy, the least expellant of the greenhouse gas CO , 2 and that the ter inalproductsw ith high value could be anufactured. It is therefore feasible that the procedure suggested in this paper is hopeful industrialized both in econo icbenefits and environ entalkindness. Key words: insoluble potassiu ore; sintering reaction; ther odyna ics; clean