混凝沉淀处理含镉废水的效果及其作用机理初探南华大学学报.PDFVIP

第28卷第3期 南华大学学报(自然科学版) Vol郾28 No郾3 2014年9月 Journal of University of South China(Science and Technology) Sep郾2014 文章编号:1673-0062(2014)03-0099-04 混凝沉淀处理含镉废水的效果及其作用机理初探 1 2 2 * 唐鹏飞 ,许文杰 ,王延飞 (1.湖南衡阳市金化科技有限公司,湖南 衡阳421001;2.南华大学 化学与化工学院,湖南 衡阳421001) 摘摇 要:混凝沉淀工艺处理含镉废水,使处理后水体的镉浓度达到《污水综合排放标 准》GB8978—1996 的0.1 mg/ L排放. 实验研究不同絮凝剂、絮凝剂投加量和初始 pH对去除镉的影响,另对混凝沉淀后的絮体进行X射线衍射分析.结果表明无机高 聚物的絮凝剂和初始pH为9 的溶液对镉的去除效果较好.随着聚合氯化铝(PAC )I 投加量增加,当PAC 盐基度为67%时,镉的去除效果明显增加.X射线衍射分析絮I 体中镉的结合形式主要为氢氧化镉和碳酸镉. 关键词:混凝;镉;聚合氯化铝;XRD 中图分类号:X703摇 摇 摇 文献标识码:B Treatment of Wastewater Containing Cadmium by Coagulation Method 1 2 2* TANG Peng鄄fei ,XU Wen鄄jie ,WANG Yan鄄fei (1.Hengyang Jinhua Company of Science and Technology,Hengyang,Hunan421001,China;2.School of Chemistry and Chemical Engineering,University of South China,Hengyang,Hunan421001,China) Abstract:The wastewater containing cadmium was treated by coagulation method.As the recovery of cadmium metal,the concentrations of cadmium in treated water reached 0郾1mg/ L of the prescribed discharge standards in “Integrated Wastewater Discharge Standard (GB8978—1996) 冶.In the process of coagulation,we studied the effect of floc鄄 culant,dosing and different pH value on cadmium removal.The experimental results show that polyaluminium chloride (PAC ) and the initial pH value of 9 on cadmium removalI effect are better.With PAC dosing quantity increasing which the basicity was 66.67%,I cadmium removal efficiency increased significantly.X鄄ray diffraction showed that the form of cadmium in the floc was cadmium hydroxide and cadmium carbonate.