铜氨络离子破络方法（Method for breaking collaterals by copper ammonia ion）.docVIP

铜氨络离子破络方法（Method for breaking collaterals by copper ammonia ion） 1. sulfide precipitation method: heavy metal ions and S2- are easy to form insoluble or insoluble sediment. Adding Na2S can completely precipitate the heavy metal ions in wastewater. Such as the CuS solubility product (Ksp=6.3 * 10-36) on the value (lgKsp (CuS) =35.2) is far greater than that of [Cu (NH3) 4]2+ and EDTA-Cu dissociation constant on the value ([Cu (NH3) 4]2+ on the numerical stability constant for lgK stability =12.59, stability constant EDTA-Cu is lgK =18.80, so adding stability) Na2S can break the complex formation, CuS precipitation. But CuS has a tendency to form colloidal solution (through filter paper), need to add flocculant to form large flocs to settle down. The treatment of PCB complex wastewater with this method is often because the sedimentation tank sedimentation effect is not good, so that the effluent can not reach the standard. In addition, due to the absence of sulfide on-line monitoring instruments, the project often requires excessive dosing of Na2S, excessive amounts of S2- make waste water foul, adding ferrous salt to precipitate it, otherwise it will cause two pollution. 2. heavy metal chelating agent: heavy metal chelating agent is a water-soluble chelate which can form stable insoluble matter with a variety of heavy metals. Heavy metal chelating agents are combined with copper ions to form a more stable chelate, forming precipitation and removal. Han min and so on the development of a new type of organic macromolecule heavy metal chelating agent (DTCR), pH was 7, DTCR/FeCl3 was 14, the stirring time was 40min, the copper removal rate as high as 99.8%, is not affected by the coexistence of [1] complexes. The treatment of complexed copper wastewater with heavy metal chelating agent is simple and convenient, but the heavy metal chelating agent has higher general price and higher treatment cost. Method: the ferrous sulfate in acidic conditions, the stable constant of E