铬酸配法（Chromic acid method）.docVIP

铬酸配法（Chromic acid method） Preparation method of chromic acid lotion Release time: 2010-05-24 21:48:24 view: 835 fonts: [large, medium and small] Preparation method of chromic acid lotion 2007-07-01 14:28 Chromic acid lotion preparation method: in 60 degrees, with 50 grams of water dissolved 25 grams of potassium dichromate powder, stir a small amount of direct, add industrial sulfuric acid (98%) 450 milliliters. According to the literature: Potassium bichromate: water: sulfuric acid =1:2:20 formula, decontamination effect is best. If there is no water, then the lotion is unstable. It will precipitate a large amount of CrO3 red precipitate after being closed for a month. The decontamination principle of Zhang Changcais aqueous chromate lotion and the experimental comparison of some prescriptions. Chinese Journal of hospital pharmacy, Vol third, third, 21-23, 1983. Laboratory vessel: rubber gloves, stirring magnet, two 500 ml Brown thin mouth bottles, 1 liters and 200 ml beaker 1. potassium dichromate: need to grind fine. Cause: the powder is more soluble. The operation is in the fume hood, because the potassium bichromate powder raised during the grinding process is harmful to the health. 2. according to the MDL CrossFire Commander 7 (Gmlin Handbook of inorganic compounds) inquiries that: 60 degrees weight percentage in saturated solution of potassium dichromate in 33.56%, conversion of 60 degrees 100 grams 50.5 grams of water soluble potassium dichromate. 3. dissolve the potassium dichromate with water at 60 degrees first, and then accelerate the preparation of the lotion. Do not cool, stir, direct, a small amount of industrial sulfuric acid (98%), each time the amount of less than 10 ml.. 4. do not use cold water bath. The reaction temperature is controlled at less than 90 degrees. The temperature is too high for water to evaporate. 5. potassium dichromate saturated solution and sulfuric acid have the following reaction: K2Cr2O7+H2SO4=K2SO4+2CrO3 (precipitation) +H