铜渣中铁组分的直接还原与磁选回收-中国有色金属学报.pdfVIP

21 5 2011 5 Vol.21 No.5 The Chinese Journal of Nonferrous Metals May 2011 1004-0609(2011)05-1165-06 ( 100083) − 39.96%() CaO 100:30:101 250 50 min85% 43µm 92.05%81.01% 30 µm TF09X758 A Iron recovery from copper-slag with lignite-based direct reduction followed by magnetic separation YANG Hui-fen, JING Li-li, DANG Chun-ge (Civil and Environmental Engineering SchoolUniversity of Science and Technology Beijing, Beijing 100083, China) Abstract: In order to recycle iron from copper slag with total iron content (TFe) of 39.96%(mass fraction), a technique with lignite-based direct reduction followed by magnetic separation was presented. After analysis of chemical composition and crystalline phase, according to experimental mechanism, the tests for studying the effects of different parameters on the recovery of iron were carried out. The results show that the optimum parameters are proposed as follows: the mass ratio of copper slag/lignite/CaO is 100:30:10, the reduction temperature is 1 250 , the time is 50 min, and the particle size of 85% roasted product is smaller than 43 µm, under which the direct reduction iron powders with TFe of 92.05% and iron recovery rate of 81.01% are obtained. After reduction, the fayalite (Fe SiO ) and magnetite 2 4 (Fe O ) in copper slag are reduced to metallic iron. The metallic iron particles whose sizes are mainly larger than 30 µm, 3 4 are loosely supported on the surface of slag particles. So the monomer dissociatio