FGD系统中内衬不锈钢合金的腐蚀行为.PDF

FGD 系統中內襯不銹鋼合金的腐蝕行為 防蝕工程　第二十四卷第四期　第211 ~ 220 頁　2010 年 12 月 Journal of Chinese Corrosion Engineering, Vol. 24, No. 4, pp. 211 ~ 220 (2010) FGD 1 1 1 1 2 林景崎* 、楊仁泓 、張庭綱 、張曾隆 、邱善得 Corrosive Behavior of Stainless Steel Alloys in an FGD System 1 1 1 1 2 J. C. Lin* , J. H. Yang , T. K. Chang , C. L. Chang , S. D. Qiu Received 1 September 2008; received in revised form 10 May 2010; accepted 26 May 2010 本研究以電化學方法來評估三種不銹鋼合金(317LM 、654SMO 及254SMO)在 FGD 系 統中做為內襯材料之適用性。實驗採用直流電極化法及交流電阻抗頻譜法，在綠色溶液腐 蝕液中評估其耐蝕性。結果顯示：317LM 不銹鋼合金在通空氣之綠色溶液環境下其鈍化膜 成長最迅速，但其鈍化膜之防蝕效果不佳。相較而言，654SMO 及 254SMO 則表現出良好 的耐蝕性，尤其 654SMO 合金在溫度較高的環境下，鈍化效果依然明顯，其鈍化膜在高溫 下仍具良好安定性。在綠色溶液中254SMO 合金鈍化膜的成長速率，會隨溫度上升而下降， 此鈍化膜會因溫度上升而被破壞。654SMO 合金具有最佳之抗蝕性。 關鍵字：綠色死亡溶液；排煙脫硫系統 ；耐蝕不銹鋼合金；高抗局部腐蝕指數。 ABSTRACT Electrochemical techniques were employed to evaluate the corrosion behavior of stainless steels (i.e., 317LM, 654SMO and 254SMO) in an attempt to select proper lining materials used in the flue gas desulfurization (FGD) system of a fossil power plant. A direct current polarization technique and alternating current impedance spectroscopy were conducted in a corrosive medium of green solution to measure the corrosion rate and compare the corrosion resistance of the specimens. The results indicated that it was faster to form a passive film on the surfac