Y41Sc15Al24Co20大块非晶合金的制备及其晶化动力-中南大学学报.PDFVIP

第 39 卷第 5 期 中南大学学报( 自然科学版) Vol.39 No.5 2008 年 10 月 J. Cent. South Univ. (Science and Technology) Oct. 2008 Y41Sc15Al24Co20大块非晶合金的制备及其晶化动力学行为 何世文，刘 咏，李占涛，吴 宏 ( 中南大学 粉末冶金国家重点实验室，湖南 长沙，410083) 摘 要：利用铜模吸铸法制备直径为 5 mm的Y41Sc15Al24Co20大块非晶合金，采用连续加热和等温加热方法对其晶 化动力学行为进行研究。利用Kissinger方程得出该合金的晶化激活能为 3.02 eV 。用Johnson-Mehl-Avrami (JMA) 方程描述合金的等温晶化过程，在不同等温温度下计算得出Avrami指数大于 3.0，合金的主要晶化过程为三维形 核长大过程。在Arrhenius方程的基础上，得到合金的区域Avrami指数和阶段晶化激活能随晶化体积分数变化的关 系曲线。 关键词：Y 基大块非晶合金；晶化动力学；Avrami 指数；晶化激活能 中图分类号：TG139.8 文献标识码：A 文章编号：1672−7207(2008)05−0962−06 Preparation and crystallization kinetics of Y41Sc15Al24Co20 bulk amorphous alloy HE Shi-wen, LIU Yong, LI Zhan-tao, WU Hong (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Y41Sc15Al24Co20 bulk amorphous alloy with a diameter of 5 mm was fabricated by the method of copper mould suction casting. The crystallization kinetics of the bulk amorphous alloy was investigated by differential scanning calorimetry (DSC) in the mode of continuous heating and the isothermal annealing. The activation crystallization energy is determined by Kissinger method, i.e. Ec=3.02 eV. And the isothermal kinetics is modeled by the Johnson–Mehl–Avrami (JMA) equation, the Avrami exponents are calculated to be 3.35–4.3 for different isothermal temperatures, which implies the crystallization mechanism is a three-dimensional nucleation and growth. Finally, the nucleation and growth behaviors during the isothermal crystallization can be ob