总磷、总氮的测定方法（Method for determination of total phosphorus and total nitrogen）.docVIP

总磷、总氮的测定方法（Method for determination of total phosphorus and total nitrogen） Determination of total nitrogen in water Alkaline potassium persulfate digestion UV Spectrophotometry 1.1 theme content This standard specifies the method of digestion and ultraviolet spectrophotometric determination of total nitrogen in water with alkaline potassium persulfate at 120~124. 1.2 scope of application For the determination of surface water and groundwater. The total amount of nitrite nitrogen, nitrate nitrogen, inorganic ammonium salt, dissolved ammonia and most organic nitrogen compounds in water can be determined by this method. The minimum detectable concentration of nitrogen was 0.050mg/L, with an upper limit of 4 mg/L. The molar absorption coefficient of the method is 1.47 * 103L.mol-1.cm-1. The main interfering substances in the determination are iodine ion and bromide ion, the iodine ion is more than 2.2 times the total nitrogen content, and the bromine ion has interference with the total nitrogen content more than 3.4 times. Certain organic compounds can not be completely converted to nitrate under the conditions determined by this law. They have an effect on the determination. 2. definitions 2.1 filtration total nitrogen: refers to the water soluble and filter solid (less than 0.45 m particles) nitrogen content. 2.2 total nitrogen: the amount of nitrogen in soluble and suspended particles. 3, principle In 60 DEG C water solution, potassium persulfate and potassium bisulfate can be decomposed to produce atomic oxygen, potassium bisulfate dissociate in solution and produce hydrogen ions, so in alkaline medium of sodium hydroxide can accelerate the decomposition process tends to be completely. The decomposed atomic oxygen can be converted into nitrate at the temperature of 120~124. And in the process, the organic compounds are simultaneously oxidized and decomposed. The absorbance A220 and A275 can be measured at 220 and 275nm wavelength respectively by ultraviolet spectro