三片食品罐外壁涂膜中有害物质向内涂的迁移-河南农业科学.PDF

194 2012, Vol. 33, No. 06 食品科学 ※分析检测 1 2 2 1 , 刘海波 ，赵宇晖 ，张作全 ，向 红 * (1.华南农业大学食品学院，广东 广州 510642 ；2.奥瑞金包装股份有限公司，北京 101407) 对制版印刷后的食品用三片金属罐外壁涂料中三聚氰胺、苯、甲苯 3 种有害物质在堆码过程中从外壁涂 膜向内涂膜的迁移扩散进行研究。采用高效液相色谱法检测 3 种常用金属罐(番茄酱罐、八宝粥罐、凉茶罐) 内壁和 外壁涂膜中三聚氰胺、苯和甲苯 3 种残留物在去离子水、3g/100mL 乙酸、体积分数 10% 乙醇3 种水性食品模拟液 中的初始迁移量。并对制罐铁片在恒温(30 ℃) 、恒湿(60 ±2)% RH 、恒压34kPa 条件下堆码 2 个月后内壁涂膜中 3 种残留物的向食品模拟液中的迁移量与堆码前进行比较分析，即外壁涂膜中这 3 种残留物向内壁的迁移扩散情况。 结果表明，3 种有害物质均有从外壁向内壁迁移的现象，迁移量达到 0.04～1.60μg/mL ，对内壁涂膜的安全性造成 极大影响，严重影响到罐装食品的安全性。 食品罐涂料；堆码储放；迁移扩散；三聚氰胺；高效液相色谱 Migration of Hazardous Substance Residues in the External Coating of Three-Piece Food Cans 1 2 2 1, LIU Hai-bo ，ZHAO Yu-hui ， ZHANG Zuo-quan ，XIANG Hong * (1. College of Food, South China Agricultural University, Guangzhou 510642, China； 2. ORG Packaging Limited Company, Beijing 101407, China) Abstract ：The migration of residual hazardous chemical agents including melamine, benzene and toluene from external can coatings to internal coatings during the stacking process was studied in this paper. A high performance liquid chromatography (HPLC) method was used to determine the substances in three different simulated aqueous food systems, including distilled water, 3% (m/ V) acetic acid solution and 10% ( V/ V) ethanol solution. The migration was monitored in the cans stacked at constant temperature (30 ℃), moisture ((60 ± 2)% RH) and pressure (3.4 kPa) for two months. It was found that all the harmful substances in the exterior coatings were migrated into the internal wall of the food cans in the migration range of 0.04 －1.60 μg/mL, which h