三相加压氧化制备锰酸钾的反应动力学-IngentaConnect.PDF

40 12 Sm Sr Al Cr O 1767 0.9 0.1 1–x x 3–δ 40 12 Vol. 40 No. 12 2 0 1 2 1 2 JOURNAL OF THE CHINESE CERAMIC SOCIETY December 2012 1 2 (1. 650093 2. 650031) 110.18kJ/mol TQ115 A 0454–5648(2012)12–1767–06 2012–11–29 10:09:55 /kcms/detail/11.2310.TQ1009.201212.1767_020.html Reaction Kinetics of Potassium Manganate Prepared by Three-phase Compression Oxidation Process 1 2 PENG Dong WANG Jikun (1. Faculty of Material and Metallurgy Engineering, Kunming University of Science and Technology, Kunming 650093, China; 2. Yunnan Metallurgy Group Parent Company, Kunming 650031, China) Abstract: Potassium manganate was prepared with manganese powder as raw material by a three-phase compression oxidation proc- ess. The factors (i.e., particle size of manganese powder, temperature and oxygen partial pressure) affecting the conversion rate of MnO2 were analyzed and the kinetic equation for each factor was obtained by the “kinetic model of shrinking core”. The apparent activation energy is 110.182 kJ/mol. The process is controlled by the surface chemical reaction. Key words: potassium manganate; manganese powder; three-phase compression oxidation; reaction kinetics (2) [1] 2K MnO +H O ⎯→K MnO +2KOH +MnO 2 3 2 2 4 [2] [3–4] [5]