北半球新能源材料-锂电池（New energy materials for the northern hemisphere lithium batteries）.docVIP

北半球新能源材料-锂电池（New energy materials for the northern hemisphere lithium batteries） Make the lithium metal keep a smooth and uniform surface in the charge discharge cycle. Significant progress has been made in the first two, but the direct use of lithium as a negative electrode is still at the stage of research. For the current development of carbon material instead of lithium metal as the most successful use of the anode material, carbon material with layered structure, can be used as the import pipeline of lithium ions, can also be used as lithium ion storage storage space, but is affected by the carbon material crystal structure, organization structure and morphology that makes many of the electrochemical problems, need to be further modified to improve the electrochemical performance expectations. Table 2 is a comparison of energy density between carbon based materials and lithium metal. 4. electrolyte function in traditional electrochemical system in most of the salt water solution as between the anode and cathode ion conduction medium, however the strong activity of lithium metal anode, a system to avoid the presence of water, with organic solution and salt solution without machine or directly using molten salt instead. Which is mainly organic liquid electrolyte. At present, there are two kinds of common electrolytes in the development of lithium ion batteries, they are liquid electrolyte and solid polymer electrolyte. 4-1 liquid electrolytes, currently used in lithium-ion batteries, are composed of lithium salts mixed with one or more organic solvents. In organic solvents, including: EC (ethylenecarbonate), PC (propylene, carbonate), EMC (ethyl, methyl, carbonate), DMC (dimethyl, carbonate) and DEC (diethyl, carbonate) and so on, are all carbonates. In terms of lithium salts are: LiAsF6, LiBF6, LiClO4 and LiPF6 and so on. Table 1-1 presents the basic physical properties of various organic solvents used in lithium ion batteries. Lithium ion battery liquid electro