氧化钕和氧化镨钕在大气中的吸水特性研究.docVIP

氧化钕氧化镨钕在大气中的吸水特性研究 邓永春1,2，崔萌萌2，吴胜利1，姜银举2，刘聪2 (1.北京科技大学 冶金与生态工程学院，北京 100083；2.内蒙古科技大学 材料与冶金学院，内蒙古包头 014010) 摘要：研究了氧化钕氧化镨钕的吸水特性及吸水稳定后物质的结构与形态表征，通过增重试验及增重稳定后物质的X射线衍射试验，讨论了氧化钕和氧化镨钕吸水的一般动力学过程，分析了影响吸水速率的因素。研究表明，氧化钕氧化镨钕的吸水过程为未反应核模型，Lageren准一级、HO准二级动力学方程仅能对其诱导期之后的某个阶段拟合较好。氧化镨钕明显异于氧化钕，吸水产物孔隙率减小，吸一定水后出现类似“饱和”的现象。 关键词：氧化钕氧化镨钕吸水特性动力学分析TF802.6 文献标志码：A 文章编号：1007-7545（2015）04-0000-00 Study on Water Absorption Characteristics of Neodymium Oxide and Neodymium Praseodymium Oxide in Atmosphere DENG Yong-chun1,2, CUI Meng-meng2, WU Sheng-li1, JIANG Yin-ju2, LIU Cong2 (1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China) Abstract: Water absorbing characteristics of Nd2O3 and neodymium praseodymium oxide, and structure and morphology characterization after stable water absorption were studied. General dynamics process of water absorbing on Nd2O3 and neodymium praseodymium oxide was checked by weighting tests and XRD of stable water absorbing materials. The factors affecting water absorbing rate were analyzed. The results show that water absorbing process of Nd2O3 and neodymium praseodymium oxide accords with unreacted core model, while equations of Lageren pseudo-first order kinetic model and HO pseudo-second order kinetic model can only fit to a certain phase after induction period. Compared with Nd2O3, neodymium praseodymium oxide has smaller porosity with saturation phenomenon after water absorbing. Key words: Nd2O3; neodymium praseodymium oxide; water absorbing characteristic; dynamic analysis 含有氟化物（REF3-LiF）的稀土氧化物熔盐体系在电解过程中，电解槽排出的尾气中含有少量的气体，严重污染环境。稀土氧化物在大气中有一定的吸水能力，可以生成稀土氢氧化物，在熔盐电解过程中，当稀土氧化物加入到熔盐表面时，由于吸水而生成的稀土氢氧化物发生分解反应，分解得到的水与熔盐中的稀土氟化物发生水解反应而放出气体[1]。氧化物吸水是稀土氧化物熔盐电解过程中产生气体的一个隐藏因素。通过对稀土氧化物吸水特性的研究从源头控制气体的产生。黄继民等[2]研究发现La2O3样品在室温下96增重量趋于平衡，完全转变成了La(OH)3，其它稀土氧化物在大气中的稳定性未见报道。 GB26451-201