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镁熔液中氢气泡析出动力学模型-中南大学学报
第 46 卷第 12 期 中南大学学报(自然科学版) Vol.46 No.12
2015年 12 月 Journal of Central South University (Science and Technology) Dec. 2015
DOI: 10.11817/j.issn.16727207.2015.12.009
镁熔液中氢气泡析出动力学模型
许四祥,侍海东,张炳刚,徐起兵
(安徽工业大学 机械工程学院,安徽 马鞍山,243002)
摘要:针对镁熔液中氢气泡的析出过程,分析氢气泡析出的动力学特性。考虑多种因素对氢气泡析出影响,对镁
熔液中氢气泡上浮运动进行受力分析,利用牛顿第二定律得出氢气泡上浮运动过程中的瞬时加速度方程,并结合
气体状态方程、传质边界层方程及流函数等相关性质,推导出镁熔液中氢气泡在析出过程中气泡速度、气泡半径、
气泡上浮高度与时间变化关系的动力学模型。采用龙格库塔算法将模型方程在 MATLAB 中进行编程计算,得到
气泡传质速率与时间及气泡半径与时间的关系曲线。研究结果表明:氢气泡形核后析出,随着上浮高度的增加,
气泡速度与半径都随之变大,加速度先增大后减小;临近界面处,气泡趋于某一速度值析出并破裂。此模型为镁
熔液中氢气泡的形成机理提供了一定的理论基础,对镁合金液态质量控制具有重要意义。
关键词:镁; 氢;动力学模型; MATLAB
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中图分类号:TG243 .1 文献标志码:A 文章编号:1672−7207(2015)12−4448−05
Kinetic model of hydrogen gas bubble evolution
in magnesium melt
XU Sixiang, SHI Haidong, ZHANG Binggang, XU Qibing
(Mechanical Engineering Institute, Anhui University of Technology, Ma’anshan 243002, China)
Abstract: The kinetic property of hydrogen was analyzed in the process of hydrogen gas bubble evolution. According to
the force analysis, a transient acceleration equation of hydrogen gas bubble in magnesium melt was established by the
Newton’s Second Law considering influential factors. Simultaneously, a kinetic model that described the changing
relation of hydrogen gas bubble velocity, radius, rising height and time was obtained by in combination with three other
equations and theoretical deduction. These equations were the boundary layer mass transfer equation, the gas state
equation
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