硼掺杂的中间相碳素微球（MCMB）用作锂离子电池负极材料的性能及表征.pdfVIP

第7卷 第3期 电化学 7 No 3 2001年 8月 Y Aug 2001 文章编号：1006—3471(2001)03-0263—07 Characterization and Electrochemical Investigation of Boron·Doped Mesocarbon Microbeads Anode M aterials for Lithium—Ion Battery CHEN Mao—hut，WU Guo—tao，ZHU Guang—ming， Y0U Jin—kua．LIN Zu—geng (State Key Lab for Physical Chemistry Sotid Surface， 0，Chert X 口 n Univ，Xiamen 361005，China) Abstract：The anodic performances of boron—doped and undoped mesocarbon microbeads (MCMBs)were comparatively studied and the structur~were characterized by XPS，SEM，XRD and dectrochemical measurements．It was found that boron-doping s~mples greatly increased the degree of graphitization and the crystallite size．1eading to quite dlfferem morphology．E1ectm— chemical di~harge／charge cycle te~tS indicate that lithiam intercalation occurred at a little higher porent[al for the boron—doped MCMBs，being attended by greater irreversible eapadty loss Key words：MCMBs，Boron-doped MCMBs，Electrochemical property，XPS，SEM，XRD CLC Number：o 646，TM 912 Document Code：A 1 Intr0ductiOn In recent years，beton-doped carbons have been recei,wxl much attention for t}1eir intercept as host ma1erials f0r 1I1hil】m imer阻【at 0n_1-3： It is convinced that boron—doping Can modify the dectronic properties of carbon graph／tic network as boron is neighboring to carbon _m periodic tab1e and has 0ne electron defident．Experimental and theoretica1 investigations pointed out that boron-doping is prompting the creation of electmn acceptor levelL ’ ．inducing positive holes in the energy band of matrix graphite，and hence improved battery performance can be expected if 1