用碳化养护电弧熔炉钢渣制备集料和混凝土-硅酸盐学报.PDF

· 1264 · 硅 酸 盐 学 报 2007 年 第35 卷第9 期 硅 酸 盐 学 报 Vol. 35 ，No. 9 2 0 0 7 年 9 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY September，2007 用碳化养护电弧熔炉钢渣制备集料和混凝土 1,2 2 2 常 钧 ，WANG Sanwu ，SHAO Yixin (1. 济南大学材料科学与工程学院，济南 250022 ；2. Department of Civil Engineering and Applied Mechanics, McGill University, Montreal, H3A 2K6, Canada) 摘 要：将电弧熔炉(electric arc furnace，EAF)钢渣和石灰混和制成球状集料，置于密闭容器当中，并通入 100%的CO2 气体进行碳化，在0.506 6 MPa 保持2 h 。通过质量法测定添加质量分数为11.94%石灰的EAF 钢渣(下同)集料CO2 的吸收率为5%，通过红外光谱(infrared, IR)分析测定CO2 的吸收率 为 13.88%。用碳化的钢渣集料制备混凝土再进行碳化养护，同时利用碎石和河砂为集料制备碳化混凝土作为参比样。用质量法测定2 种混凝土的碳 化率分别为21.14%和10.57%；用IR 法的为13.81%和16.97%。碳化后电弧熔炉钢渣集料内生长着大量簇生的犬牙状碳酸钙晶体。 关键词：电弧熔炉钢渣碳；碳化养护；集料；二氧化碳；碳酸钙 中图分类号：TQ178 文献标识码：A 文章编号：0454–5648(2007)09–1264–06 MANUFACTURE OF ELECTRIC ARC FURNACE SLAG AGGREGATE AND CONCRETE THROUGH CARBONATION CURING CHANG Jun 1,2 2 2 ，WANG Sanwu ，SHAO Yixin (1. School of Materials Science and Engineering, University of Jinan, Jinan 250022, China; 2. Department of Civil Engineering and Applied Mechanics, McGill University, Montreal H3A 2K6, Canada) Abstract: The aggregate consists of pelletized particles produced from a mixture of hydrated lime and electric arc furnace (EAF) slag. The pellets were injected into 100% CO2 gas at a constant pressure of 0.506 6 MPa for 2 h in a closed chamber. The CO2 contents of the carbonated materials were measured. The CO2 uptake of EAF slag mixed with hydrate