硫酸中及常用材料的耐腐蚀曲线图.pptVIP

对冷却水中氯离子的耐腐蚀曲线 Typical Composition of Metals for Use in Heat Exchangers in H2SO4 Processing 硫酸板式换热器使用材料： 稀酸：镍合金SMO254:浓度10％以下，温度75℃以下，Cl根3000ppm 氟离子 1000ppm以下; 浓酸：哈氏合金C276：浓度93％以上，温度90℃以下 密封垫片：稀酸三元乙丙橡胶EPCM，浓酸氟橡胶FKMG，半焊接式换 热器板片密封可不用氟橡胶 铜电解液换热器使用材料：在介质浓度不变的条件下，影响腐蚀的二大因素是温度和接口流速； 硫酸下使用的材料：SMO254和哈市合金G30（比C276耐Cl根和氟根优越） Ti：在硫酸铜介质中，可到105℃ 接口流速对板片腐蚀的影响：通常金属表面形成的氧化膜抵抗介质的腐蚀， 大多数氧化膜对流速是敏感的； 板式换热器中，通道流速，分流区和接口流速中，接口流速最快，当电解液循环流量超过设计流量时，接口流速增加 Plate - main components Frame - M15 and larger Unique 5-point alignment system Provides exact positioning of the plates horizontally and vertically Ensures good sealing throughout the plate pack Sulphuric acid 10 102 103 104 105 0 50 100 Temperature °C No corrosion 316 C-276 254 SMO Crevice corrosion D-205 pH = min 7.0 ppm chlorides N 0.2 W W 3, Fe 2-6 W 2.5, Fe 18-21 Si 5, Fe 6 Si max.0.08 AISI 316 Avesta 254 SMO Alloy C-276 Hastelloy C-22 Hastelloy G-30 Hastelloy D-205 Hastelloy C-2000 17.0 20.0 15.5 21.0 29.5 20.0 23.0 12.0 18.0 58.0 44.0 40.0 64.5 59.0 2.0 6.1 16.0 13.5 5.0 2.5 16.0 0.7 1.7 2.0 1.6 Others Cr Nickel Mo Cu Composition Iso-corrosion diagram 0.1 mm/year Diabon Hastelloy D-205 254 SMO Hastelloy C-276 Alloy G-30 AISI 316 AISI 316 150 100 50 0 °C 150 100 50 0 °C 0 10 20 30 40 50 60 70 90 80 100% 硫酸中常用材料的耐腐蚀曲线图 Thin sheet design, cold formed in single step hydraulic pressing (up to 40000 tons) Main heat transfer area Distribution area Suspension Inlet / outlet Passing through Gasket in gasket groove Leak chamber Carrying bar Guiding bar Plate In order to understand the differences between C276 and D205, it is necessary to know some facts about the materials and the alloys involved. Both materials are Nickel alloys, which means that they have 30% Nickel. Nickel stabilises the material. Chromium and Molybdenum give the material good resistance towards chloride ions, Molybdenum being the most