Sn晶须的形态机制-中国有色金属学报.PDF

第 19 卷第 2 期 中国有色金属学报 2009 年 2 月 Vol.19 No.2 The Chinese Journal of Nonferrous Metals Feb. 2009 文章编号：1004-0609(2009)02-0308-07 Sn 晶须的形态机制 郝 虎，董文兴，史耀武，夏志东，雷永平 (北京工业大学 材料科学与工程学院，北京 100124) 摘 要：将稀土相 CeSn3 与 ErSn3 暴露于空气中，研究在时效处理过程中稀土相表面 Sn 晶须的形态机制。结果表 明：时效过程中在稀土相表面出现的绝大多数 Sn 晶须均是具有恒定截面的规则 Sn 晶须；同时也发现少数特殊形 态的不规则 Sn 晶须，如卷曲状的 Sn 晶须、变截面的 Sn 晶须、分枝及搭接的 Sn 晶须等；由于稀土相的氧化所产 生的体积膨胀提供 Sn 晶须生长的驱动力，而稀土相的氧化极不均匀，因此，认为 Sn 晶须在生长过程中其根部受 力状态的改变是导致特殊形态 Sn 晶须出现的根本原因。 关键词：无铅钎料；稀土；Sn 晶须；形态 图法分类号: TN 601 文献标识码: A Mechanism of tin whisker morphology HAO Hu, DONG Wen-xing, SHI Yao-wu, XIA Zhi-dong, LEI Yong-ping (School of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China) Abstract: The morphological mechanisms of tin whisker growth on the surface of oxidized CeSn and ErSn precipitates 3 3 were investigated during the aging. The results indicate that most tin whiskers have constant cross section and regular shape. However, few irregular tin whiskers with special morphologies are also observed, including the spiral whiskers, whiskers with a non-constant cross section, branch-type whiskers and joining-type whiskers. Since the produced lattice expansion of the rare earth precipitates oxidization provides driving force for the tin whisker growth, and the oxidization is extremely uneven. Therefore, the changes of stress around the tin whisker root will primary cause that results in the growth of irregular tin whiskers. Key words: lead-free solder; rare earth; tin whisker; morphology 在电子产品的封装互连中，