无溶剂微波法合成咪唑基离子液体的研究-南昌航空大学期刊网.PDFVIP

50 , , , (, 330063) []; ; ; [ ] 1- N- ( [ bm mi ] BF ), 4 ; , , , 280W, 5, 95. 7% [] O64416 [ ] A [] 1001- 4926( 2010) 02- 0050- 05 Study on the Syn thesis of Im idozole Ion ic liqu id s w ith Solven t- freeM icrowave M ethod s IU Guo- qing, ZHONG Rong, WANG Hong- liang, X iong Fang (N anchang H angk ong Un iv ersity, N anchang, J iangx i 330063, Ch ina) K ey w ord s: m icrowave methods; ion ic liqu ids; synthesis; solvent- fre A bstract: In th is paper, by m icrow avem ethod, the synthesis of mi idozole ion ic liqu idswas studied and the productwas identified by FT- IR. The reaction yieldsw ere m ainly effected on m icrow ave pow er and reaction tmi e, but they w ere solvent m ed ias, reaction tem perature and reaction tmi e w ith the traditional solventw ay. The results show ed that the reaction of ion ic liqu ids synthesisw ere eff-i cient by m icrow avem ethod. The best conditions of the synthesiswere that the m icrow ave pow erw as280W and the reaction tmi e was 5 m inu tes. The yield can reach to 95. 7% . 1914, Sudgen , [ 1] ( 2071- 2072) : ( 1) [ 1] ( 2071- 2072) 20 80, W ilkes [ 6] ; ( 2), 1, 3- , N - , ; ( 3) 1, 3- , [ 2- 4] , , , , [ 5] [ 7- 8] ( green solvents) , [] 2010- 01- 16 [] 2010- 04- 22 []江西省教育厅科技基金项目基于离子液体- 光引发剂的合成与性能( DB200902143 ); 南昌航空 学科研基金项目季铵盐 光产碱剂的合成与性能研究( E20060239