复合碱媒介法合成棒状CdTe晶体SynthesisofCdTeMicro-crystal.PDF

2011 年第69 卷 化 学 学 报 Vol. 69, 2011 第13 期, 1540～1544 ACTA CHIMICA SINICA No. 13, 1540～1544 ·研究论文· 复合碱媒介法合成棒状 CdTe 晶体 项东虎 朱亚波* 罗 锦 郭立童 ( 中国矿业大学材料科学与工程学院 徐州 221116) 摘要 以Te 粉和Cd(NO ) 为原料, 以联胺为还原剂, 采用复合氢氧化物媒介法, 在不同的反应条件下分别合成了棒状 3 2 和立方体状的CdTe 晶体, 其中棒状CdTe 晶体的横向尺度为2～3 µm, 纵向尺度达几十微米. 选择反应温度为180 ℃ 并在反应体系中适量加水, 将有助于棒状CdTe 的形成, 并提出了CdTe 晶体的生长模型. X 射线衍射图谱(XRD) 以及紫 外-可见分光吸收谱测试表明, 合成的棒状CdTe 结晶性好, 吸收峰值位于近红外, 能带带隙值约为1.49 eV. 关键词 碲化镉; 复合碱媒介法; 吸收光谱; 带隙 Synthesis of CdTe Micro-crystal Rods by Composite- hydroxide-mediated Method Xiang, Donghu Zhu, Yabo* Luo, Jin Guo, Litong (School of Materials Science and Engineering, China University of Mining and Technology, Xuzhou 221116) Abstract CdTe micro-crystal has been successfully synthesized by composite-hydroxide-mediated method (CHM) using Te and Cd(NO ) as the reactants and hydrazine hydrate as reductant. The rod- and 3 2 cube-shaped CdTe have been obtained under the different reacting conditions. The length of the rods was up to about several decades of micrometers. It will be helpful to the forming of rod-shaped CdTe with appropri- ate deionized water added into the reacting system at temperature of 180 ℃. Here a new model was pro- posed to describe the growth for CdTe crystal. XRD pattern indicates that rods were well crystallized. UV-visible absorption spectrum of the rods exhibits a peak