溶胶-凝胶法制备双钙钛矿结构Sr2FeMoO6多晶体-河北工程大学.PDFVIP

28 1 ( ) Vol1 28 No11 2011 3 Journal of Hebei Universi y of Engineering ( Na ural Science Edi ion) Mar12011 : 1673- 9469 ( 2011) 01- 0060- 04 - Sr FeMoO 2 6 杜晓燕, 门高夫 ( , 0560 38) : 采用溶胶- 凝胶法在烧结温度为1 373K 条件下制备出了双钙钛矿结构的Sr2 FeMoO6 合 物, 并通过X 射线衍射分析原子力显微镜分析热重- 差示扫描量热分析以及PPMS 测试系统 对样品的表面形貌相形成以及磁学性能进行了分析结果表明: 制备的样品为纯相, 颗粒度均 匀, 晶界清晰, 品质较高; 当烧结温度大于1 023K 时, 即可成相; 在外场为30 000Oe 下, 温度为 10K 和300K 时样品的磁电阻分别达到16. 25% 和5% : 溶胶- 凝胶法; 热分析; 双钙钛矿; 磁电阻 : O482. 5 :A Prepara ion of double- perovski e poly- crys al compound Sr FeMoO 2 6 by sol- gel me hod DU Xiao-yan , MEN Gao-fu ( School of Science, Hebei Universi y of Engineering, Hebei Handan 056038, China) Abstract:The double- perovski e Sr FeMoO compound have been prepared a 1 373K by sol- gel me h- 2 6 od. The sample. s microcosmic shapes, phase forma ion and Magne ic proper ies were sys ema ically inves- iga ed by means of X- ray diffrac ome er, a omic force microscope, he hermogravime ric- DSC analysis and Physical Proper y Measuremen Sys em ( PPMS) . The resul s indica ed ha he prepared sample is pure phase, he sample par icle size uniformi y, grain boundary clear and higher quali y. And if he sin er- ing empera ure is higher han 1 023K, he sample will become phase. When ex ernal field is 30 000Oe and he empera ure of he sample for he 10K and 300K, magne oresis ance is 16. 25% and 5% res