聚氨酯胶粘剂论文.docVIP

摘 要 紫外光固化技术是近些年来为行内竞相开发的新兴技术，广泛应用于涂料、胶粘剂等领域。而紫外光固化胶粘剂是利用此项技术达到迅速固化的一类胶粘剂。由于其具有储存时间长、不含溶剂、固化速度快、透明性好以及耐热耐化学品性能好等特点，在研究和易用方面引起了人们极大地关注。伴随着“5E原则”的提出，光固化胶粘剂取代传统胶粘剂在生产中展现了良好的前景。 本文主要对玻璃用紫外光固化胶粘剂的制备、性能及应用进行了研究。紫外光固化胶粘剂主要由预聚物、光引发剂、活性稀释剂和其它助剂组成。预聚物构成了光固化材料的基本骨架并决定着产品的最终性能。光固化聚氨酯丙烯酸酯胶粘剂因其分子结构中含有丙烯酸酯和氨基甲酸酯键，固化后材料兼具有聚氨酯的高耐擦伤性、柔韧性、高撕裂强度和优良的低温性能以及聚丙烯酸酯卓越的光学性能和耐候性，是一种极有发展前途的辐射固化胶粘剂。 本文采用甲苯2,4-二异氰酸酯(TDI)、低聚物二元醇和甲基丙烯酸羟丙酯(HPMA)为原料,通过溶液法、多步反应合成聚氨酯丙烯酸酯预聚物，对每步合成条件进行了详细的研究，讨论低聚物二元醇种类、溶剂种类及-NCO/-OH比等因素对反应及产物性能的影响，由此找到最佳合成条件。并以此预聚物为主体，通过添加光引发剂、复合活性稀释剂和其他助剂等制成紫外光引发胶粘剂。研究了光引发剂和稀释剂的种类和用量等因素对光固化体系的影响。最后使用玻璃片进行粘接，对其力学性能和其他性能进行测试。实验结果表明：在自制的聚氨酯丙烯酸酯胶粘剂中，低聚物多元醇使用聚乙二醇600，反应单体比例为2:1:1，活性稀释剂使用甲基丙烯酸甲酯，含量为30%，此时胶粘剂的粘接性能达到最佳，其他性能也同时较佳。 关键词：紫外光固化；聚氨酯丙烯酸酯；预聚物；胶粘剂 Abstract Uv-curing technology is developed in recent years for the emerging technology industry competes, widely used in coating, adhesive, etc.While uv-curable adhesive is using the technology to achieve rapid solidified type adhesives.Since it has stored for a long time, do not contain solvent, curing speed, transparency, good heat resistance to chemicals and performance is good wait for a characteristic, in research and easy to cause the people greatly concerned.With the principle of “5E”uv-curable adhesive to replace traditional adhesive production showed good prospects. This paper focuses on the glass with uv-curable adhesive preparation, properties and application were studied.Uv-curable adhesive mainly by pre-polymer,photoinitiators,active diluents and otheradditives.Pre-polymer constitute the basic framework of the uv-curable materials and determines the final product.Uv-curable polyurethane acrylates adhesives for its molecular structure contains acrylate and carbamate keys, after curing polyurethane materials and has high resistance to scratch, flexibility, high temperature and high tear strength and excellent performance polyacrylic acid ester of optical properties and weathering resistance, is a very promising radiation curing a