超细晶wc-10co硬质合金制备的主要影响因素-有色金属科学与工程.docVIP

超细晶WC-10Co硬质合金制备的主要影响因素 张贺佳1 ，陈礼清1, *， 王文广2，孙 静1, 王全兆3 （1.东北大学轧制技术及连轧自动化国家重点实验室，沈阳 110819；2.辽宁石油化工大学机械工程学院，抚顺 113001；3.中国科学院金属研究所，沈阳 110016） 摘 要：利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)以及力学性能测试分析，研究了不同粒度的WC和Co原始粉末经不同时间球磨后的微观形貌；并对球磨后的复合粉末添加不同配比的晶粒抑制剂，进行真空热压烧结制备了超细晶硬质合金，考察了不同配比的晶粒抑制剂对超细晶硬质合金组织和力学性能的影响。结果表明，使用原始细颗粒粉末，经较短时间的球磨处理就可以达到较好的细化效果；复合添加VC + Cr3C2或VC + TaC晶粒抑制剂对硬质合金晶粒的细化效果明显好于单一添加VC的细化效果；添加Cr3C2后WC晶粒呈近圆形，且硬质合金抗弯强度有明显提高；添加TaC后的WC晶粒呈三角或四边形，促进硬质合金的硬度提高。 关键词：超细晶硬质合金；WC-10Co；晶粒抑制剂；微观结构；力学性能 中图分类号：TG 146.4 文献标志码：A Main Factors Influencing Preparation of Ultra-fine Grained WC-10Co Cemented Carbide ZHANG he-jia1, CHEN li-qing 1, *, WANG wen-guang 2, SUN jing 1, WANG quan-zhao 3 (1. State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China; 2. School of Mechanical Engineering, Liaoning Shihua University, Fushun 113001, China; 3. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China ) Abstract: By using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and measuring mechanical behaviors, microstructures of WC and Co powders with different initial particle sizes were investigated after different times of ball milling. The ball milled composite powders with different percentage of grain growth inhibitors were vacuum hot-pressed and sintered to prepare ultra-fine grained cemented carbides and the microstructure and mechanical properties of the as-prepared cemented carbide were studied to reveal the effect of grain growth inhibitor. The results show that the ultra-fine raw powder material has a good effect after a short time of ball milling. The grain refining effect in cemented carbide by adding VC+Cr3C2 or VC+TaC is better than that after sole adding of VC. The WC particles has a round shape and the bending strength of the cemented carbide can be improved by adding Cr3C2, while the WC particles take shapes of triangle or quadrilateral and the hardness can be improved by adding VC. Key words: Ul