低磷浓度下鸟粪石结晶成粒及反应器流态模拟-北京玛格泰克科技发展.pdfVIP

中国环境科学 2016,36(4) ：1017~1026 China Environmental Science 低磷浓度下鸟粪石结晶成粒及反应器流态模拟 杨 露,平 倩,李咏梅* ( 同济大学环境科学与工程学院,污染控制与资源化研究国家重点实验室,上 200092) 摘要：为扩大鸟粪石(MAP)结晶成粒技术的应用范围,对低磷浓度下 MAP 成粒最优条件进行了研究.试验得出该技术应用的磷浓度应大于 50mg/L,并在此基础上研究得到低磷浓度条件下 MAP 结晶成粒的最佳条件:pH 9.0,磷氮物质的量比 1:8.此时生成的 MAP 平均粒径为 3 0.56mm,总体积生长率为 4.95cm /h,纯度可达 99.9%.为进一步优化流化床反应器中 MAP 成粒条件,利用 CFD 商用软件(Fluent 6.3)对反应器 流态进行了模拟.结果表明:MAP 流化床反应器的生长区能够形成明显的自下而上的水力分级,截面流速也较为均匀,有利于颗粒的生成,但 沉淀区和进水区存在死区、涡流等不利条件.因此,有必要改进生长区和沉淀区的连接方式以及进水管的分布, 以获得更为优质的MAP 颗粒. 关键词：鸟粪石成粒；低磷浓度；最佳条件；颗粒品质；CFD 流态模拟 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2016)04-1017-10 Struvite pellet crystallization at low phosphorus concentration and fluidization simulation of the reactor. YANG Lu, * PING Qian, LI Yong-mei (State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China). China Environmental Science, 2016,36(4) ：1017~1026 Abstract ：In order to expand the application field of struvite (MAP) pellet crystallization technology, the optimal conditions for struvite pellet formation at low phosphorus concentrations were investigated. Results show that the phosphorus concentration over 50mg/L would be better for application of this technology. The optimal conditions for struvite pellet formation were as follows: pH = 9.0 and phosphorus to nitrogen molar ratio = 1:8. Under the conditions, the average size of harvested struvite particle reached 0.56mm, the volume growth rate was 4.95cm3/h and the struvite purity reached 99.9%. In order to further optimize MAP formation in the fluidized bed reactor, CFD software (Fluent 6.3) was used to simulate t