扩链剂对脂肪族聚氨酯脲和聚脲弹性体结构与性能的影响.pdf

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第16 期, 1737～1742 ACTA CHIMICA SINICA No. 16, 1737～1742 ·研究论文· 扩链剂对脂肪族聚氨酯脲和聚脲弹性体结构与性能的影响 杨 娟 王贵友* 胡春圃 (华东理工大学材料科学与工程学院 上海 200237) 摘要 用异佛尔酮二胺(IPDA)、乙二胺(EDA)和己二胺(HDA)三种扩链剂合成了不同结构的脂肪族聚氨酯脲和聚脲, 并 考察了扩链剂对聚氨酯脲和聚脲形态结构与性能的影响. 研究结果表明, 与EDA 和HDA 扩链的聚氨酯脲和聚脲相比, IPDA 扩链的聚氨酯脲和聚脲中脲羰基的氢键化程度较低, 软段和硬段间的相混合程度较好; 同时它们具有更好的拉伸 强度、硬度和撕裂强度, 但断裂伸长率较低. EDA 和HDA 扩链的聚氨酯脲和聚脲相比, 两者性能相差不大. 聚氨酯脲 的脲羰基较完善氢键化程度以及整个氢键化程度都比聚脲的要低, 同时聚氨酯脲的吸水率也较低. 关键词 脂肪族聚氨酯脲; 脂肪族聚脲; 形态; 氢键; 力学性能 Effect of Chain Extenders on Structures and Properties of Aliphatic Polyurethaneureas and Polyureas YANG, Juan WANG, Gui-You* HU, Chun-Pu (School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237) Abstract A series of aliphatic polyurethaneureas (PUUs) and polyureas (PUAs) with various chain ex- tenders were prepared. The influence of chain extenders on morphology and properties of these polyure- thaneureas and polyureas was studied. The PUUs and PUAs synthesized with isophorone diamine (IPDA) showed lower degree of hydrogen bonding for the urea carbonyl groups existed in the system as well as bet- ter miscibility between soft and hard segments, compared to those prepared with ethylenediamine (EDA) or hexanediamine (HDA) as chain extenders. The tensile strength, hardness and tear strength of PUUs and PUAs prepared with IPDA