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Y-PSZ固体电解质电性能的厚度尺寸效应研究
Y-PSZ
Research on the thickness effect of
Electrical Properties of the Solid
Electrolytes in Y-PSZ
Thesis Submitted to
Tsinghua University
in partial fulfillment of the requirement
in
Materials Science and Engineering
by
Fei Zhaoyang
Thesis Supervisor: Professor Gong Jianghong
May, 2013
(SOFC)
5mol%
50μm~1.5mm XRD
SEM
Cole-Cole
0.02S/cm
Arrhenius Arrhenius
1.0eV
ZrO2
I
Abstract
Solid oxide fuel cell (SOFC) is recognized as one of the most advanced fuel
cell today. A variety of electrolyte materials have been used in SOFC, and the
most remarkable one is ZrO2 stabilized with oxides of trivalent metals. It is
thoroughly researched and most widely used nowadays.
In this article, 5 mol% yttria-stabilized Zirconia was prepared by the
casting method. By changing process parameters, three different groups of
samples were produced, with thickness of each set ranging from 50μm to 1.5mm.
By XRD, the Archimedes method and SEM, the crystal structure, density and
surface morphology were determined.
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