PA6二氢辣椒碱功能纤维的制备及其性能研究.pdf

Preparation and properties of PA6/dihydrocapsaicin functional fibers A Dissertation Submitted for the Degree of Master Candidate：HuangHuahai Supervisor：Associated Prof. Yan Yu rong South China University of Technology Guangzhou, China 摘要 二氢辣椒碱具有抗菌，驱虫等优异的性能，可应用于医疗保健及化工材料等领域。 本文通过酰胺化反应制备出高纯度二氢辣椒碱，通过红外，核磁，元素分析进行结构表 征，采用热性能分析确定其熔点为57.85℃，热分解温度274.66℃。二氢辣椒碱对大肠 杆菌(革兰氏阴性菌代表，ATCC25922)有优异的抑菌和杀菌作用，其最小抑菌浓度（MIC） 为 25ug/ml,最小杀菌浓度（MBC）为25ug/ml。二氢辣椒碱对对小黑蚁有较为明显的驱 避作用，且随其浓度的增加驱避作用越强，但该驱避作用不具备杀灭效果，可推断二氢 辣椒碱对小黑蚁的驱避作用是通过接触刺激所引起的。 通过调节二氢辣椒碱的含量，可制备具有不同抗菌性能要求的PA6/二氢辣椒碱功能 纤维毡，且其抗菌性能随着洗涤次数的增加而逐渐降低，洗涤十次后的抗菌率为94.58%。 并且纤维毡抗菌作用起效快，于3 小时内抗菌率便达到97%。 本文通过对复合纤维毡的力学性能研究发现，随着二氢辣椒碱含量增加，断裂应力， 断裂比功，断裂伸长率及初始模量均呈先增大后减小的趋势。控制二氢辣椒碱的含量有 助于改善纤维毡的力学性能。 二氢辣椒碱/PA6 复合纤维毡对蚁虫具有良好的驱避作用，二氢辣椒含量为 8%时， 对小黑蚁的驱避率为70%。主要是通过纤维中的二氢辣椒碱与蚂蚁接触而产生刺激驱避 效应。 关键词：二氢辣椒碱；静电纺；尼龙6；抗菌；蚁虫驱避； I Abstract Because of its excellent biological activity,dihydrocapsaicin can be used in many fields just like the field of biological medicines, biomaterial,medical care material and so on. The high high purity dihydrocapsaicin,which was synthesised by amidation,had been characterized by FTIR,NMR,EI etc.The melting point is 57.85 ℃,and the thermal degradation point is 274.66 ℃.The antibacterial activity of dihydrocapsaicin to Escherichia coli had been cornfirmed in this research,and the Minimum inhibitory concentration (MIC) and the Minimum bactericidal concentration (MBC) is 25ug/ml respectively. The repellent effect to ants of dihydrocapsaicin had been investigated,and we had found that the repellent effect,which belongs to the stong irritant,