四酸溶样-电感耦合等离子体原子发射光谱法测定铁铜锌铅等硫化.PDF

# # Bulletin of Mineralogy, Petrology and Geochemistry Vol1 30 No1 1, Jan1 2011 - 22 马生凤, 温宏利, 马新荣, 王 蕾, 巩爱华, 曹亚平, 屈文俊 , 100037 : 本实验应用四酸( 硝酸, 盐酸, 氢氟酸, 高 酸) 混合溶矿, 电感耦合等离子体原子发射光谱法( ICP- AES) 同时测定了铁 矿石铜矿石铅矿石锌矿石及多金属矿石样品中AlFeCuPbZnCaMgKNaSbMnTiLiBeCdAgCoNiSrV Mo 和S 22 个元素量实验确定了方法的分解条件以及测定元素的检出限及干扰条件用国家 一级标准物质 GBW07162( 多 金属贫矿石) 和GBW07163( 多金属矿石) 进行精密度实验, 统计数据显示, 结果精密度( RSD) 和准确度( RE) 都小于10% , 而且 大多数元素的精密度和准确度在5% 范围内通过标准物质进行方法验证, 非单矿物或精矿的一般硫化物矿石的检测结果基 本都在标准值的范围内, 符合地质矿产开发的要求本方法具有同时测定元素多线性范围宽检出限低等优点, 实际使用性 强, 结果满意 : 铁铜锌铅等硫化物矿石; 电感耦合等离子体光谱; 四酸熔矿 : P575 : A : 1007-2802(2011) 01-0065-08 Determination of 22 Elements in Iron, Copper, Zinc, and Lead Sulphide Ores by ICP-AES with our Acids Digestion MA Sheng-feng, WEN Hong-li, MA Xin-rong, WAN G Lei, GONG Ai-hua, CAO Ya-ping, QU Wen-jun N at io nal R esear ch Center f or Geoanaly sis , B eij ing 100037, Ch ina Abstract:This paper presents a method to determine 22 elements of AlFeCuPbZnCaMgKNaSbMnT i LiBeCdAgCoNiSrVMo and S in sulphide ores, including ironstone, copper ore, lead and zinc ore and mult-i metal ore by Inductively Coupled Plasma Atomic Emission Spectrometry ( ICP-AES) using nitric acid, hydro- chloric acid, hydrofluoric acid and perchloride acid for sample digestion. The techniques for sample dissolution, de- tection limits and spectrum interference of coex isting elements w ere studied, and the optimal analytical wavelengths were selected. The accuracy and precision of this method were examined by analyzing different reference materials. The results were in a