多壁碳纳米管固相萃取净化-食品安全质量检测学报.pdfVIP

7 4 Vol. 7 No. 4 2016 4 Journal of Food Safety and Quality Apr. , 2016 - 26 * 陈啟荣 , 杨 明, 梁 颖, 朱琳娜, 邵 鹏, 范筱京 (, , 100089) 摘 要: 目的 - 26 方法 , , 结果 , , 26 0.04~1.6 µg/mL 0.005~0.05 mg/kg, 0.015~0.15 mg/kg , 66.6%~125.5%, 0.3%~6.4%(n=5) 结论 , 关键词: ; ; ; Determination of 26 pesticides in tea by gas chromatography-mass spectro- metry with multi-walled carbon nanotubes as solid-phase * CHEN Qi-Rong , YANG Ming, LIANG Ying, ZHU Ling-Na, SHAO Peng, FAN Xiao-Jing (Beijing Center for Physical and Chemical Analysis , Beijing Engineering Research Center of Food Safety Analysis , Beijing 100089, China) ABSTRACT: Objective To determine 26 pesticides in tea by solid-phase extraction with multi-walled car- bon nanotubes and gas chromatography-mass spectrometry (GC-MS). Methods The sample was extracted with acetonitrile. After purified by multi-walled carbon nanotubes, the sample solution was detected by GC-MS. Results The established method was simple, and could reduce the pesticides decomposition in pretreatment. The calibration curves of 26 pesticides were linear in the range of 0.04~1.6 µg/mL. The limits of detection for 26 pesticides in tea were in the range of 0.005~0.05 mg/kg, and their limits of quantitation were 0.01