单分散微纳米卤化银乳剂的光吸收特性研究——立方体乳剂和氯化银.PDFVIP

2006 年第64 卷 化 学 学 报 Vol. 64, 2006 第9 期, 833～838 ACTA CHIMICA SINICA No. 9, 833～838 ·研究论文· 单分散微/纳米卤化银乳剂的光吸收特性研究—— 立方体乳剂和氯化银{100}面扁平颗粒乳剂 李 智 郑 彤 彭必先 陈丽娟* ( 中国科学院理化技术研究所 北京 100101) 摘要 重点研究了系列立方体乳剂和氯化银{100}面T-颗粒乳剂的光吸收特性. 通过调变乳剂制备的各项参数, 成功地 制备了系列立方体卤化银乳剂及氯化银{100}面扁平颗粒乳剂. 经过TEM 和SEM 进行观察, 统计颗粒的形貌、粒径, 确 定系列立方体乳剂微晶的粒径分别为: 80, 150, 600 nm; 得到的氯化银{100}面扁平颗粒乳剂微晶的等效粒径为 1400 nm, 且形态比不小于7. 经过对明胶-乳剂层和片基的反射和透射光谱测试, 计算了不同形貌、不同粒径AgCl(Br)乳剂 体系的光吸收系数, 比较了相对光吸收能量. 实验发现: 纳米级卤化银立方体的光吸收在可见光谱区始终保持有较高 值, 主要吸收峰与其它颗粒相比明显发生了红移; 氯化银{100}面T-颗粒乳剂在本征吸收区及可见光区域都有独特的光 吸收性能. 关键词 氯化银乳剂; 纳米尺度; {100}面扁平颗粒; 立方体颗粒; 光吸收 Light Absorption Properties of Monodispersed Micron/Nano-sized Silver Halide Emulsions: Cubic Silver Halide and AgCl {100} T-grain LI, Zhi ZHENG, Tong PENG, Bi-Xian CHEN, Li-Juan* (Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101) Abstract A silver chloride {100} T-grain emulsion and a series of cubic silver halide emulsions were pre- pared by varying the parameters correctly during nucleation and growing processes of grains. After the ob- servation of SEM and TEM, following statistical data were obtained: the diameters of the cubic microcrystal are 80, 150, 600 nm respectively, the equivalent circular diameter (ECD) of the {100} tabular microcrystal is 1400 nm and the shape ratio (ratio of ECD to thickness of a grain) is not less than 7. The absorbencies and the relative absorbed energy of the emulsions were calculated and then compared with each other. It