六角形二硫化锡纳米片：一种新型的可见光催化剂.doc

六角形二硫化锡纳米片：一种新型的可见光催化剂 韩志陶、常洪勋、史飞、朱兆强、肖伟 安阳师范学院化学化工学院，安阳，河南，455002 摘要：以SnCl4·5H2O和CS2为前驱物，利用一种改进的溶剂热方法成功合成了六角形SnS2单晶纳米片，利用X射线衍射（XRD）、透射电子显微镜（TEM）和高分辨透射电子显微镜（HRTEM）对所得产物的物相、形貌以及晶格进行了表征。结果表明，所得SnS2纳米晶为具有六角片状形貌的单晶六方结构，其直径为20-70nm、厚度为7-10nm。结构和高分辨透射电镜分析表明，SnS2纳米片的六角片状形貌来源于其{001}晶面的生长受限以及其六个等能量、高指数的{110}晶面的快速生长。以罗丹明B（Rh B）的水溶液为模拟染料废水，进一步研究了所得SnS2六角纳米片在可见光条件下对染料的光催化降解性能。实验数据表明，所得SnS2纳米片对罗丹明B水溶液具有很好的光催化降解能力，在太阳光照射70分钟后的脱色率可达97.7%。良好的光催化性能表明，SnS2纳米片是一种性能优异的可见光催化剂，在环境保护、废水处理方面具有很好的应用前景。 Hexagonal tin disulfide nanoplatelets：A new photocatalyst driven by solar light Han Zhitao, Chang Hongxun, Shi Fei, Zhu Zhaoqiang, Xiao Wei College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan, 455002 ABATRACT：Single-crystalline, hexagonal tin disulfide (SnS2) nanoplatelets were successfully synthesized through an improved solvothermal process with SnCl4·5H2O and carbon disulfide (CS2) as precursors. The crystal phase, morphology, and crystal lattice of the prepared products were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM), respectively. Results reveal that the synthesized SnS2 nanoplatelets are in hexagonal structure with 20-60nm in diameter and 7-10nm in thickness. The structural and HRTEM analysis indicates that the formation of SnS2 nanoplatelets with hexagonal morphology results from the accelerating growth of six energetically equivalent high-index crystalline planes {110} and the retarded growth of {001} crystalline planes. The photocatalytic degradation properties of hexagonal SnS2 nanoplatelets driven by solar light were further investigated with Rhodamine B (RhB) as simulating pollutant. Results show that these SnS2 nanoplatelets have a good performance of photocatalytic degradation on RhB, and the decolorizing rate can reach 97.7% after irradiated for 70 minutes by solar light. Better photocatalytic properties indicate that hexagonal SnS2 nanop