第二届结构工程新进展国际论-坛文模-cnki.docVIP

第七届海峡两岸及香港钢结构技术交流会暨第五届结构工程新进展论坛论文模板( 张一三1,2，李四2 (1. 大连理工大学 海岸和近海工程国家重点实验室, 辽宁 大连 116023; 2. 同济大学 土木工程防灾国家重点实验室, 上海 200092) 摘 要：为了改善钢铁材料的耐高温腐蚀性能, 用光束合金化方法在45钢表面合成了Fe-Al金属间化合物涂层. 采用扫描电子显微镜、能量弥散X射线分析和X射线衍射研究了光束合金化工艺参数(粉末预置量m和热输入量q)对合金化层的化学成分、显微组织及其物相组成的影响. 实验结果表明: 减小比能量(E＝q/m)将导致合金化层的熔宽和熔深减小, 从而使合金化层含Fe量减少, 含Al量增加;该实验条件下, 获得了Fe与Al原子数比为2.4～19.2的合金化层. 由比能量决定的Fe与Al原子数比是合金化层显微组织及其物相组成的重要影响因素, 合金化层的显微组织有3种类型: α-Fe固溶体、α-Fe固溶体+Fe3Al金属间化合物及FeAl+AlFe3C0.5金属间化合物. 降低热输入或增加粉末预置量均可引起合金化层中Fe与Al原子数比的降低,有助于Fe-Al系(Fe3Al或FeAl)金属间化合物的合成. 关键词：表面合金化; Fe-Al金属间化合物; 光束合金化涂层; 微观组织 ：THE FIFTH INTERNATIONAL FORUM ON ADVANCES IN STRUCTURAL ENGINEERING Y.S. Zhang1,2，2 (1.State Key Laboratory of Coastal and Offshore Engineering, Dalian University of Technology, Dalian 116023, China; 2. State Key Laboratory for Disaster Reduction in Civil Engineering, Tongji University, Shanghai 200092, China.) Abstract: The high temperature corrosion resistance of steel was improved with a Fe-Al intermetallic coating applied to Steel-45 by light beam alloying. The effect of alloying processing parameters (the pre-placed powder mass, m, and the heat input, q) on the chemical composition, microstructure and phases of the alloying coatings was investigated by scanning electron microscopy, energy dispersive X-ray analysis, and X-ray diffraction. The results show that reducing the specific heat input E (E=q/m) reduces the width and penetration of the alloying molten pool, which reduces the Fe content and increases the Al content of the coatings. The experiments resulted in coatings with 2.4-19.2 Fe/Al atomic ratios. The Fe/Al atomic ratio determined by the specific heat input is the most important factor affecting the microstructure and phases of the coatings. There are three kinds of coating microstructures, α-Fe solid solution, α-Fe solid solution + Fe3Al intermetallic compound, and FeAl + AlFe3C0.5 intermetallic compounds. Reducing the heat input and increasing the pre-placed powder mass both reduce the Fe/Al atom