金属化丙烯酸醋橡胶微球的制备及其电性能.pdfVIP

2008 年 8 月 北京航空航天大学学报 August 2008 第34 卷第8 期 Journal of Beijing University of Aeronautics and Astronautics Vo l. 34 No.8 金属化丙烯酸醋橡胶微球的制备及其电性能 詹茂盛 高达利 (北京航空航天大学材料科学与工程学院，北京 100191 ) 摘 要:采用化学镀方法，对微米级丙烯酸醋橡胶(ACM , Acrylate rubbers) 微球进行 表面金属铜镀覆;通过对镀铜反应进程的控制，制备出了镀层致密、包覆均匀的低密度 ACM 核-铜壳结构复合导电微球(简称镀铜 ACM 复合微球) ;研究了镀铜 ACM 复合微球表面铜镀层 的结构、形貌及微球的电性能.结果表明:应用化学镀的方法可以对 ACM 微球进行表面金属铜 镀覆;通过控制镀液中 OH- 的补加量，能够准确控制化学镀铜反应进程及表面镀层包覆程度; 不同包覆程度的镀铜 ACM 复合导电微球的体积电阻率均随外加压力增大而降低，几乎不随通 电时间变化，但随温度升高表现出阻四温特性. 关键词:橡胶微球;铜镀层;化学镀;电阻率 中图分类号: TB 34 文献标识码:A 文章编号: 1001-5965 (2008) 08-0911-05 Fabrication and electricity properties of metal covered acrylate rubber microspheres by electroless plating Gao Dali Zhan Maosheng (School of Materials Science and Engineering , Beijing University of Aeronautics and Astronautics , Beijing 100191 , China) Abstract: Electroless copper plating on acrylate rubber (ACM) microspheres of micron scale was stud- ied. By introducing a reaction control method , the continuously and uniformly covered ACM conductive micro- spheres with low density and core-shell structure were achieved. The morphology and composition of Cu coat- ings and the electrical properties of the Cu-coated ACM microspheres were investigated. It was found that Cu can be plated on the surface of ACM microspheres by electroless plating. The reaction process of electroless copper plating can be controlled by adjusting the OH - additional amounts , thus to control the morphology of Cu coatings. The Cu-coated ACM microspheres all present resistance characters that the volume resistivity de- c