阻燃型含磷脂环族环氧树脂的合成及其性能synthesisandproperties.pdfVIP

第 33 卷 第 6 期 辐射研究与辐射工艺学报 J. Radiat. Res. Radiat. Process. Vol.33, No.6 2015 年 12 月 /fushe/CN/volumn/home.shtml December 2015 阻燃型含磷脂环族环氧树脂的合成及其性能 韩丹丹 贾小琴 李永杰 王 涛 （北京化工大学理学院有机化学系 北京 100029 ） 摘要 以不同比例的 10-(2,5-二羟基苯基)-10-氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO-HQ)和 3,4-环氧环己基甲 基-3,4-环氧环己基甲酸酯(ERL4221)进行反应，合成不同含磷量的阻燃型环氧树脂(EP-HQ)，并用红外光谱及 核磁共振对其结构进行了表征。测试了不同磷含量对环氧树脂的环氧值、热性能、阻燃性能和紫外光固化性 能的影响。结果表明，同ERL4221 相比，EP-HQ 的热稳定性和阻燃性有所提高，当磷的质量分数为 1.5%时， EP-HQ 的氧指数达到24.9% ，垂直燃烧达到了V-1 ，且具有较高的光固化活性。 关键词 紫外光固化，含磷环氧树脂，合成，热稳定性，阻燃性 中图分类号 TL13 DOI: 10.11889/j.1000-3436.2015.rrj.33.060302 Synthesis and properties of flame retardant phosphorus-containing cycloaliphatic epoxy resin HAN Dandan JIA Xiaoqin LI Yongjie WANG Tao (Department of Organic Chemistry, College of Science, Beijing University of Chemical Technology, Beijing 100029, China ) ABSTRACT UV-curable phosphorus-containing epoxy resin was synthesized with chain-extension of (3,4-epoxycyclohexyl)methyl-3,4-epoxycyclohexanecarboxylate (ERL4221) and 2-(6-oxido-6H-dibenz(c,e) (1,2)- oxaphosphorin-6-yl)-1,4-benzenediol (DOPO-HQ) at different stoichiometric ratios. The structures of these resins were characterized by IR and 1H-NMR. The influences of different phosphorus contents on the epoxy value of the epoxy resin, thermal properties, flame retardancy, and UV curing properties were investigated. The results showed that the thermal stability and flame resistance increased compared with those of the unmodified ERL4221 epoxy resin under the same conditions. When the phosphorus mass content was 1.5%, the limiting oxygen index (LOI) reached 24.9, vertical burning achi