硬软煤质量比变化对煤吸附甲烷的影响-采矿与安全工程学报.pdfVIP

第30 卷 第1 期 采矿与安全工程学报 Vol.30 No.1 2013 年01 月 Journal of Mining Safety Engineering Jan. 2013 文章编号：1673-3363-(2013)01-0118-051 硬软煤质量比变化对煤吸附甲烷的影响 李树刚，赵鹏翔，林海飞，潘红宇，成连华 (西安科技大学能源学院，陕西 西安 710054) 摘要 在单一煤体吸附甲烷的基础上，选用山西某煤矿同一进风巷硬软煤，按不同质量比进行分 层混合。运用 Langmuir 单分子层吸附理论，对硬软煤处于不同质量比条件下混合煤样对其吸附 特性的影响进行了实验研究。得出吸附量随硬软煤质量比变化的关系曲线、吸附常数 a ，b 随硬 软煤质量比变化关系式及瓦斯放散初速度 ΔP 随硬软煤质量比变化关系式，对瓦斯涌出受硬软煤 质量比变化的影响进行了理论分析。分析结果表明软煤质量和其上部硬煤质量近似相等时，吸附 常数 a 及放散初速度 ΔP 达到最大值，吸附常数 b 达到最小值。这一发现说明了在此情况下，煤 对甲烷的吸附量及其压力均达到最大值，一旦扰动此类煤层，便会形成较大的压力梯度及浓度梯 度，发生大量瓦斯涌出，研究结果对煤与瓦斯突出机理提供了理论基础。 关键词 硬软煤质量比；吸附特性；吸附常数；瓦斯放散初速度 中图分类号 TD 712.6 文献标志码 A Effect of mass ratio change of hard and soft coal on adsorption of methane gas LI Shu-gang ，ZHAO Peng-xiang ，LIN Hai-fei ，PAN Hong-yu ，CHENG Lian-hua (College of Energy Science and Engineering，Xi’an University of Science Technology ，Xi’an ，Shannxi 710054，China) Abstract In this paper, based on gas adsorption by the single coal body, both the hard and soft coal samples were chosed in the same air-intaking entry of one mine in Shanxi, and the samples were mixed hierarchically according to different quality ratio. In addition, the influence of mixed samples on gas adsorption characteristics under different quality ratios of hard and soft coal bodies were studied in the laboratory, by using Langmuir single molecule layer absorption theory. Then, the curves of adsorption quantity variation, the variation equation of adsorption constants a, b, and the initial speed of methane emission ΔP , with different mass ratios of hard and soft coal bodies, were obtained.