抗冲共聚聚丙烯的组成及其结晶行为.PDFVIP

  77 结构与性能 合 成 树 脂 及 塑 料 ， 2017，34（1）：  CHINA SYNTHETIC RESIN AND PLASTICS        抗冲共聚聚丙烯的组成及其结晶行为 * 施红伟，刘宣伯，郭梅芳，宋文波 （中国石油化工股份有限公司北京化工研究院，北京市 100013） 摘 要： 采用二甲苯可溶物分析仪和分析型升温淋洗分级仪表征了两种二甲苯可溶物含量相近、二甲苯可 溶物中乙烯含量不同的抗冲共聚聚丙烯（IPC ）。利用溶解沉淀法分离出两种IPC试样的室温可溶物，得到了两个室 温不溶物。采用非等温结晶和等温结晶方法研究了两种IPC原样及室温不溶物的结晶行为。采用小角X射线散射方 法研究了两种IPC原样及室温不溶物的片晶厚度和长周期。结果表明：在二甲苯可溶物含量相近的前提下，二甲苯 可溶物对不溶物结晶行为的影响与二甲苯可溶物中的乙烯含量有关。在二甲苯可溶物中乙烯含量较低的试样中， 不溶物的结晶受可溶物的影响更明显。 关键词： 抗冲共聚聚丙烯 化学组成 结晶行为 升温淋洗升级 中图分类号： + 文献标识码： 文章编号： TQ 325.14 B 1002-1396（2017）01-0077-04 Chemical composition and crystallization of IPC Shi Hongwei，Liu Xuanbo ，Guo Meifang，Song Wenbo （Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 100013，China ） Abstract ： Two impact polypropylene copolymers（IPC）with similar xylene soluble（XS）content and different ethylene content in XS（C in XS）were characterized by XS analyzer and analytical temperature rising 2 elusion fractionation（A-TREF）. Two soluble and two insoluble fractions were removed at room temperature from two IPCs by means of dissolution-precipitation method. The crystallization behavior of two IPCs and two insoluble fractions were observed by non-isothermal and isothermal crystallization respectively. The long period and the lamella thickness of two IPCs and insoluble fractions were determined by small angle X-ray scattering （SAXS）respectively. The results show that C in XS exerts impact on crystallization behavior of the