纳米硫化锌的制备及应用.doc

学生毕业论文（设计） 题 目： 纳米硫化锌的制备及应用 姓 名：曾凯 学 号：200901020534 系 别：化学工程系 班 级：化工0915班 指导教师：佘媛媛讲师 2011 年 12 月 5 日 摘要 本论文对纳米硫化锌的性质、应用及制备方法进行了详细综述，并在此基础上提出了在超声波作用下用氧化锌和硫化钠溶液反应合成纳米硫化锌的制备方法及纳米硫化锌的应用研究。纳米硫化锌在催化、光电、磁性、力学等方面具有优异的性能，其制备方法也成为研究的重点。本实验考查了反应温度，反应时间，超声波振荡时间，物料配比等因数对纳米硫化锌纯度、粒度及形貌的影响，得出最佳反应条件为:反应温度90℃，硫化钠浓度20mol/L，反应时间2h，反应前超声分散10min。纳米硫化锌粒子受量子效应和介电限域效应等的影响，往往具有不同于块体材料和原子或分子的介观性质，在材料学、物理学、化学、催化和环保等方面具有广阔的用途，能够以悬浮液、多孔膜、表面修饰或催化等多种形式应用于各个领域。 关键词：纳米硫化锌 超声波 温度 物料配比， 反应时间 ABSTRACT Nanoscience and technology and the rise of the 20th century has been the rapid development of a new subject. Due to the special nano zinc sulfide surface effect, volume effect, quantum size effect and macroscopic quantum tunneling, so that in catalytic, optical,magnetic, mechanical, etc. to show many exotic physical and chemical properties, has many important applications, has been a research focus. These excellent performancelargely depends on the particle size of ZnS nanoparticles prepared in different particle size, narrow distribution of nano-ZnS nanoparticles as inorganic materials chemistrytopics at the forefront, so the preparation method of a nano-ZnS focus of the study, this paper made ??the corresponding description. The paper used in the ultrasonic irradiation of zinc oxide and sodium sulfide solution reaction preparation of nano-ZnS, and by controlling the reaction temperature, reaction time, ultrasonic vibration time, material ratio and otherfactors. Experiment the optimum reaction conditions: reaction temperature 90 ℃, sodium sulfide concentration of 20mol / L, reaction time 2h, ultrasonic dispersion before reaction10min. Nano-ZnS particles by quantum effect and dielectric confinement effect and other effects are often different from that of bulk materials and atomic or molecular mesoscopicnature of the materials science, physics, chemistry, catalysis and environmental protectionhas a broad purposes. Nano-ZnS enough to suspensions, poro