B位离子的种类对介孔La0.6Pr0.4BO3复合氧化物 的催化性能影响.pdfVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2017, 7(5), 225-235 Published Online September 2017 in Hans. /journal/hjcet /10.12677/hjcet.2017.75032 Study on Catalytic Properties of Mesoporous La0.6Pr0.4BO3 Composite Oxide in the High-Pressure Liquefaction of Bagasse * Junjiang Teng, Ning Li , Xiaohua Zhang, Xue’en Liu School of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming Guangdong th th th Received: Aug. 27 , 2017; accepted: Sep. 10 , 2017; published: Sep. 19 , 2017 Abstract Cationic surfactant CTAB as organic template agent mesoporous, La0.6Pr0.4BO3 (B = Mn2+, Cu2+, Co2+, Fe3+, Ni2+) perovskite-type oxide were synthesized by co-precipitation method. The crystalline structures, surface topography, superficial area, pore size distribution and surface properties were characterized by XRD, FI-IR, BET and temperature programmed technology; at the same time, the catalytic performances of B-site ions replaced of mesoporous La0.6Pr0.4BO3 perovskite and li- quefaction product distributions and yield of liquefied oil in the process were studied. The results showed that Mn2+ ions replaced of mesoporous La0.6Pr0.4MnO3 characteristic diffraction peaks rel- atively stronger, higher degree of crystallinity of the sample, preferably channel, having a larger specific surface area, is 21.98 m2·g−1 and the most probable pore size is 32.27 nm and stronger surface conductivity and oxygen species alkaline center, the yield of liquefied oil is 59.68% and rate of residue is 12.62% on bagasse high-pressure liquefaction reaction. At the same time, the main components of liquef