介孔丝光沸石的制备及其对重芳烃转化反应的催化性能-催化学报.PDFVIP

第 30 卷 第 12 期 催 化 学 报 2009 年 12 月 Vol. 30 No. 12 Chinese Journal of Catalysis December 2009 文章编号: 0253-9837(2009)12-1197-06 研究论文: 1197~1202 介孔丝光沸石的制备及其对重芳烃转化反应的催化性能 祁晓岚, 陈雪梅, 孔德金, 郑均林, 袁晓红, 杨德琴 中国石油化工股份有限公司上海石油化工研究院, 上海 201208 摘要：用不同浓度的 NaOH 溶液对丝光沸石进行处理制备了具有复合孔道结构的介孔丝光沸石, 并采用 X 射线衍射、扫描电 子显微镜、透射电子显微镜和 N2 吸附-脱附等方法对其进行了表征. 结果表明, 随着 NaOH 溶液浓度的升高, 介孔丝光沸石的 粒径逐渐变小, 分子筛表面的介孔逐渐丰富, 孔径分布逐渐变宽, 介孔体积逐渐增大呈线性关系. 当 NaOH 浓度为 0.50 mol/L 时, 介孔丝光沸石的形貌变为空心沸石微囊或微囊壁. 介孔的增加产生扩散效应, 适当的 NaOH 溶液处理有利于提高丝光沸石 对 C9 和 C 10 芳烃的转化能力. 关键词：丝光沸石; 碱处理; 介孔; 孔径分布; 重芳烃 中图分类号：O643/TQ53 文献标识码：A Preparation of Mesoporous Mordenite and Its Catalytic Performance for Transformation of Heavy Aromatics * QI Xiaolan, CHEN Xuemei, KONG Dejin , ZHENG Junlin, YUAN Xiaohong, YANG Deqin Shanghai Research Institute of Petrochemical Technology, SINOPEC, Shanghai 201208, China Abstract: Mesoporous mordenite samples were prepared by treatment in NaOH solution with different concentrations. The samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and N2 adsorption-desorption methods. The NaOH concentration had a great impact on physicochemical properties of the mesoporous mordenite. With the increase in NaOH con- centration, the particle size of the mesoporous mordenite became smaller, the amount of derived mesopores increased, the pore size distribu- tion became broader, and the volume of mesopores increased in a linear mann