水库淤泥合成沸石及群青颜料之研究AStudyontheSynthesisof.PDF

臺灣鑛業，第 65 卷第 3 期，第 19-27頁，民國 102 年 9月 水庫淤泥合成沸石及群青顏料之研究 A Study on the Synthesis of Zeolites and Ultramarine Pigment from Reservoir Sediments 陳冠廷 1 雷大同 2 Kuanting Chen 1 , Dahtong Ray 2 摘 要 水庫淤積之整治包括二項重要工作，一為淤泥之清除，另一為淤泥之資源化，後者尤為 重要，否則不僅容易產生二次公害，亦阻礙清淤工作之展開。本研究之水庫淤泥樣品採自桃 園石門水庫，淤泥礦物組成主要為石英、伊萊石及綠泥石。將淤泥與不同濃度之 NaOH溶液 混合，固 /液比 =1/15 ，在240℃下進行水熱反應，可合成方沸石、氫氧鈣霞石及氫氧方鈉石 等沸石類礦物，其中氫氧鈣霞石在 750~850℃可進一步與碳酸鈉、硫及活性碳混合，以固態 反應方式合成群青顏料，提供水庫淤泥資源化的一個新途徑。 關鍵詞：水庫淤泥、水熱反應、氫氧鈣霞石、青金石、群青。 Abstract The resolution of reservoir silt problems consists of two major works: one is the removal; the other is the utilization of the sediments. The latter is even more important, because if it is not solved, the sediments without proper disposition will interrupt the removal operation. The samples of this study were taken from Shih-Men Reservoir, Taoyuan. Quartz, illite and chlorite are the major mineral constituents. The sediments were mixed with NaOH solutions of various concentrations. Analcime, hydroxycancrinite and hydroxysodalite were synthesized by the hydrothermal reactions carried out at 240℃ with the solids/liquid ratio of 1/15. The TAO hydroxycancrinite was further mixed with sodium carbonate, sulfur and active carbon. At 750~850℃, ultramarine pigment can be synthesized via solid-state reaction. It is expected that the results of this study can offer a new utilization of reservoir sediments. Key words:reservoir sediments, hydrothermal reaction, hy