刺激响应性刚柔嵌段共聚物的自组装stimuli鄄responsive-大学化学.pdfVIP

第29卷 第2期 摇 摇 大 学 化 学 Vol.29 No.2 摇 2014年4月 UNIVERSITY CHEMISTRY Apr.2014 摇 刺激响应性刚柔嵌段共聚物的自组装 张金龙摇 张洁摇 宛新华 (北京大学化学与分子工程学院摇 北京 100871) 摇 摇 摘要摇 刚柔嵌段共聚物是指刚性链段和柔性链段以共价键相连形成的共聚物。 不仅由于刚性链段有序 排列的特点使得其自组装行为更为丰富多样,而且刚性分子将优异的功能特性赋予到超分子组装体中,有望 实现超分子材料的功能应用。 这类嵌段共聚物在溶液中自组装形成的聚集体会对外界的刺激(例如pH、光、 温度、化学添加剂等)敏感,产生聚集体形态的变化。 本文选取了部分典型的具有刺激响应性的刚柔嵌段共 聚物,介绍了其智能自组装行为,并对其良好的发展前景做了展望。 摇 摇 关键词摇 嵌段共聚物摇 自组装摇 刚柔性摇 刺激响应性 Stimuli鄄responsive Self鄄assembly of Rod鄄coil Block Copolymers Zhang Jinlong摇 Zhang Jie摇 Wan Xinhua (College of Chemistry andMolecular Engineering,Peking University,Beijing 100871,P.R.China) 摇 摇 Abstract摇 Rod鄄coil block copolymers (BCPs) constitute both of rigid rod鄄like blocks and the flexible coil鄄like blocks through the covalent connection. Due to the orientation tendency of rod blocks,rod鄄coil BCPs can not only self鄄assemble into various supramolecular structures,which are more distinct than their coil鄄coil counterparts. As a unique typeoffunctionalbuildingblocks,therodsegmentalsoendowthesupramolecularmaterialswithvariousappli鄄 cations. The sensitivity of supramolecular morphologiesto multiple external stimuli,such aspH,light,temperature, and chemical additives,renders its promising application as smart materials. This review highlights some valuable contributions in thepastyearsonthe self鄄assembly behavior of stimuli鄄responsiverod鄄coil BCPs,andthetrendinthe development of thisfield has also been discussed. 摇 摇 Key Words摇 rod鄄coil block copolymer;self鄄assembly;stimuli鄄responsive 摇 摇 分子自组装就是分子与分子在平衡条件下,依赖分子间非共价键力(氢键、静电作用、疏水作用、 [1]