反相乳液法淀粉丙烯酰胺接枝共聚反应的研究-高校化学工程学报.pdfVIP

20 3 No.3 Vol.20 2006 6 Journal of Chemical Engineering of Chinese Universities June 2006 1003-9015(2006)03-0460-04 1.2 1 1 1 1 2 , , , , , (1. , 530004; 2. , 510006) / / // TQ316.343 TS235.2 O623.626 A Graft Co-polymerization of Acrylamide onto Starch in Inverse Emulsion SHANG Xiao-qin1,2 1 1 1 , TONG Zhang-fa , LIAO Dan-kui , HUANG Zu-qiang , ZHANG You-quan1, ZHENG Cheng2 (1. College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China; 2. College of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China) Abstract: Graft co-polymerization of acrylamide onto cassava starch in a five-component inverse emulsion system, starch/monomer/emulsifier/water/oil, was conducted with (NH ) S O as initiator. The effects of 4 2 2 8 reaction temperature, ratio of starch to acrylamide monomer, concentrations of initiator and emulsifier, and the ratio of oil to water on the conversion of acrylamide, graft percent and graft efficiency were investigated. Meanwhile, the graft co-polymerization mechanism in inverse emulsion was described primarily. The results show that the influences of reaction temperature, ratio of starch to acrylamide monomer and initiator concentration on graft co-polymerization are predominant among the five factors mentioned above. The emulsifier content and the ratio of oil to water are two main factors for forming inve