全自动直读光谱法测定生铁中 8 种元素.pdfVIP

全自动直读光谱法测定生铁中8 种元素 ·1 · 全自动直读光谱法测定生铁中8 种元素 刘步婷 杨 琳 王 鹏 伍智娟 （湖北武汉钢铁集团公司质量检验中心, 湖北武汉 430083 ） 摘 要 应用全自动直读光谱法测定了生铁中8 种元素。提出了采用HB3000 型磨样机制样，并探讨磨样参数的优 化以及白口化程度对光谱测量的影响。优化了氩气纯度及流量、分析条件、光谱仪的清理等影响因素，给出了全自 动分析的过程质量控制手段。在优化的试验条件下，8 种元素的相对标准偏差（n=11 ）均小于5%。方法用于生铁 试样分析，测定结果与X 射线荧光光谱法的测定结果基本一致。 关键词 直读光谱法，生铁，硅，磷 Determination of 8 Elements in Pig Iron by Full Automatic Direct-Reading Spectrography Liu Buting, Yang Lin, Wang Peng, Wu Zhijuan (Quality Inspection Center of Wuhan Iron and Steel Group Company, Wuhan 430083, China) Abstract Full automatic direct-reading spectrography was applied to determination of 8 elements in pig iron. The samples was prepared with HB3000 sample grinder, and optimizing the grinding sample parameters was discussed, and spectral measurement was impacted by the level white in pig iron. Influential factors, including argon gas purity and flow rate, analytical conditions and cleaning of spectrography were optimized. The method of process quality control of automatic analysis was provided . Under the optimized experimental condition, values of RSD’s (n=11) of 8 elements found were less than 5%.The proposed method was applied to analysis of sample of pig iron, and results obtained were in conformity with by XRFS. Key words direct-reading spectrography, pig iron, silicon, phosphorus 铁水预处理作为转炉炼钢的前重要工序，直接关系到炼钢的工序简化和钢的质量提升，也是降低炼钢费 用的关键。因此，入炉铁水的各元素含量控制适当并稳定是化验室和炼铁车间共同关注的焦点。传统的铁水 预处理只集中在硅、磷、硫的成分和有效控制，随着科技的迅猛发展，对钢材质量的要求日新月异，转炉炼 钢工艺很难满足生产要求，很多元素诸如铜、砷、钛、锰、铬等的控制都前移到铁水预处理工艺上来，为此 ， 铁水中各元素及时准确的分析对指导炼铁车间冶炼具有重要意义。 [1] [2] [3] 当前的化验室主要采用X 射线荧光光谱法 、电感耦合等离子体原子发射光谱法 、分光光度法 等测