稀土硫化物的合成与反应性能的研究-有机化学专业毕业论文.pdf

StudiesOnthe and ofLanthanide SynthesesReactis’ity Thiolate Complexes ABSTRACT nliS articledescribesthe andcharacterizationsoffour1anthanide syntheses IZ complexes：[(CH3CsH4)!Ln( tO￡一 Sm(SPh)3(HMPA)3and【(CH3C5H4)2Y(p—i-OPt)]!．Theirreactivity and wasalsostudied．Theresultsobtained caprolactonephen3’lisothiocyanates areas followings： 1．The reactionsof lanthanide withPhSHin1：1 tricyclopentadienylcomplexes molarratioin THF the gave 3was (Ln=Sm(1)，Nd(2)，La(3))．Complexcharacterizedby IR．and determination．111eindicatesthatthe isa X—ray X-rayanalysis complexes dimerin the which nine．coordinatemetalcentresiS COOrdinatedtwo by sulfuratomsandaTHFmolecule methylcyclopentadienylrings．tWO 2．Thereaction withone of alcoholin of(CHjC；H4)3Yequivalent isopropyl the whichwas tetrahydrofuran gave characterizedelemental by analysis．IR．andX—ray cr3．’stallography．Thecomplex hasadimeriestructureformedtwomolecules by bridgedtogether． 3．Thereaction PhNCSwasstudied of[(cH3C5H4)2Ln(uSPh)(THF)二!with anditwasfoundthat inserts L