去除半导体废水中氟化物以合成冰晶石之研究.pdfVIP

Water Pollution and Treatment 水污染及处理, 2017, 5(3), 49-56 Published Online July 2017 in Hans. /journal/wpt /10.12677/wpt.2017.53007 Removal of Fluoride from Semiconductor Wastewater to Synthesize Cryolite * Yu-Chi Chang, Chu-Chin Hsieh , Kuan-Yu Lin Department of Safety Healthy and Environmental Engineering, National Yunlin University of Science and Technology, Yunlin Taiwan rd rd th Received: Jul. 3 , 2017; accepted: Jul. 23 , 2017; published: Jul. 26 , 2017 Abstract The issue of fluoride pollution recently has attracted much attention. Beside that the popularity of 3C products, the treatment of fluoride wastewater from semiconductor industry is worthy to be studied and discussed. In this study, the fluoride-containing solution was treated with cryolite crystallization method. The fluoride was removed by the addition of aluminum salts and sodium hydroxide to produce valuable cryolite by-product. Several parameters of process such as fluorine and aluminum molar ratio, pH, and different initial concentrations of fluoride might affected the composite of cryolite and fluoride removal efficiency, which was investigated in batch experi- ments. Then, different aluminum salts to removal efficiency were investigated with imitative sem- iconductor wastewater. Finally, the properties of material were analyzed by X-ray Diffraction (XRD) and Scanning Electron Microscope (SEM). The results showed that adjusting fluorine and aluminum molar ratio in theoretical stoichiometry of cryolite and controlling pH could recycle fluoride ion validly and produce cryolite success