单步溶胀聚合法制备单分散分子印迹聚合物微球-高校化学工程学报.PDFVIP

21 1 No.1 Vol.21 2007 2 Journal of Chemical Engineering of Chinese Universities Feb. 2007 1003-9015(2007)01-0116-06 1,2 1 , (1. , 510640; 2. , 354300) (PS)PS (MIPBs)MIPBs 1.50 µm PS 27~60 4.5 µm~6.0 µm MIPBs MIPBs MIPBs Scatchard MIPBs , Kd Qmax 8.61 mmol⋅L− 1 48.50 µmol⋅g− 1 MIPBs 1.96 ; ; ; ; TB383 TQ316.345 TQ325.2 A Preparation of Monodisperse Molecularly Imprinted Polymer Beads by a Single-Step Swelling and Polymerization Method ZHENG Xi-ming1,2, TU Wei-ping1 (1. The School of Chemical and Energy Engineering, South China University of Technology, Guangzhou 510640, China; 2. Department of Chemistry and Environment Engineering, Wuyi University, Wuyishan 354300, China) Abstract: Uniformly sized polystyrene particles (PS) with diameters of micrometer class were prepared by emulsifier-free polymerization. Using the prepared PS as seeds, naringenin as template molecules, monodisperse molecularly imprinted polymer beads (MIPBs) were prepared by a single-step swelling and polymerization method. The effects of swelling ratio and the dosage of assistant porogen—cyclohexanol on particle size and morphology of the MIPBs were investaged. It is found that the monodisperse MIPBs with particle diameters of 4.5~6.0 µm can be obtained by using 1.50 µm P