H13 模具钢中纳米析出物提取方法的探究.pdfVIP

H13 模具钢中纳米析出物提取方法的探究 ·1 · H13 模具钢中纳米析出物提取方法的探究 郭 闯 郭汉杰 （北京科技大学冶金与生态工程学院，北京 100083） 摘 要 为研究 H13 模具钢在不同的淬火、回火温度下以及不同位置析出物的类型、微观结构和粒度分布，进而 通过对纳米析出物的控制实现钢铁材料的组织性能强化。实验中采用非水溶液电解的方式提取分离钢中的析出物， 并针对 H13 钢的特点对电解液的配方进行了研究与优化，设计了一种以甲醇、乙酰丙酮、氯化锂为主，并辅以多 种添加剂的电解液，严格控制了常规非水溶液电解中的结晶和胶体干扰等现象，并将电解液的 pH 值稳定在 7~8 的 范围内。使用高分辨率透射电子显微镜对分离物进行观察，获得了拥有完整形貌和微观结构的电子图像，特别是尺 寸在 10nm 以下范围内的对钢材起到明显析出强化作用的纳米析出物，并初步验证碳化析出物的形成机理。 关键词 H13 ，纳米析出物，非水溶液电解，析出强化，形成机理 Exploration of the Extraction Method on Nano-depositionin H13 Die Steel Guo Chuang, Guo Hanjie (University of Science and Technology Beijing, School of Metallurgical and Ecological Engineering, Beijing 100083, China) Abstract Through the study of the type, microstructure and size distribution of the deposition under different quenching and temperingtemperature or different position, people can strengthen the performance of the steel by controlling the precipitation of the nano-deposition. Non-aqueous solution electrolysis method is used to extract the deposition in the steel, a study and optimum proposal on the electrolyte formulais raised according to the characteristics of H13 steel in this paper, designing a type of electrolyte mixed with methyl alcohol, diacetylmethane, LiCl and some other additives, strictlycontrolling the crystallization and the interference of colloid in traditionalelectrolysis with non-aqueous solution, and stabilizing the pH fluctuation between 7~8. Observing the isolates with HRTEM, researchers get the electronic image with integral morphology and microstructure, especi