铜负载螯合树脂对氨氮的解吸及循环吸附性能-中南大学学报.PDFVIP

第 46 卷第 11 期 中南大学学报( 自然科学版) Vol.46 No.11 2015 年 11 月 Journal of Central South University (Science and Technology) Nov. 2015 DOI: 10.11817/j.issn.1672-7207.2015.11.004 铜负载螯合树脂对氨氮的解吸及循环吸附性能 周康根，陈泉洲，姜科，胡元娟，彭佳乐 ( 中南大学 冶金与环境学院，湖南 长沙，410083) 摘要：以铜负载螯合型阳离子交换树脂(R-Cu)为新型氨氮吸附剂，研究解吸剂种类、解吸剂加入量、循环流量对 R-Cu 树脂的氨氮解吸率的影响，得到树脂的氨氮酸解吸动力学方程，通过循环实验，考察解析后 R-Cu 树脂的氨 氮吸附性能。研究结果表明：HCl 对氨氮的解吸效率高于 CH COOH 和 CO 对氨氮的解吸效率；当湿树脂中 HCl 3 2 用量为 0.75 mol/L、解析时间为 80 min、循环流量为 12 L/h 时，氨氮解吸率可达 93% ；氨氮解吸动力学基本符合 准二级动力学方程；经吸附–解吸循环 5 次后，R-Cu 树脂对氨氮的吸附性能保持稳定。 关键词：载铜树脂；解吸；吸附；氨氮；循环 中图分类号：X703.1 文献标志码：A 文章编号：1672−7207(2015)11−3999−06 Ammonia-nitrogen desorption and circulating adsorption ability of copper loaded chelating resin ZHOU Kanggen, CHEN Quanzhou, JIANG Ke, HU Yuanjuan, PENG Jiale (School of Metallurgy and Environment, Central South University, Changsha 410083, China) Abstract: Copper loaded chelating resin (R-Cu) was prepared as a novel ammonia-nitrogen absorbent. The effects of the species of desorbent, the dosage of desorbent, and the circulation flow on desorption efficiency of ammonia-nitrogen were studied. The equations of ammonia-nitrogen desorption kinetics were obtained. The circulating ammonia-nitrogen adsorption abilities of the R-Cu resin were investigated by circulation experiment. The results show that the desorption ability of HCl is better than that of CH COOH and CO . The desorption efficiency of ammonia-nitrogen is 93% at HCl 3